Hostname: page-component-54dcc4c588-r5qjk Total loading time: 0 Render date: 2025-10-06T18:56:59.905Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of Transition Metal Oxides By A NonhydrolyticSol-Gel Process

Published online by Cambridge University Press:  21 February 2011

Pascal Arnal ,
Robert J.P. Corriu ,
Dominique Leclercq ,
P. Hubert Mutin  and
Andre Vioux
Pascal Arnal
Affiliation:
UMR 44, CNRS/ Rhône-Poulenc/ Université Montpellier II, case 007, Université Montpellier II, Place E. Bataillon, 34095 Montpellier cedex 5, France.
Robert J.P. Corriu
Affiliation:
UMR 44, CNRS/ Rhône-Poulenc/ Université Montpellier II, case 007, Université Montpellier II, Place E. Bataillon, 34095 Montpellier cedex 5, France.
Dominique Leclercq
Affiliation:
UMR 44, CNRS/ Rhône-Poulenc/ Université Montpellier II, case 007, Université Montpellier II, Place E. Bataillon, 34095 Montpellier cedex 5, France.
P. Hubert Mutin
Affiliation:
UMR 44, CNRS/ Rhône-Poulenc/ Université Montpellier II, case 007, Université Montpellier II, Place E. Bataillon, 34095 Montpellier cedex 5, France.
Andre Vioux
Affiliation:
UMR 44, CNRS/ Rhône-Poulenc/ Université Montpellier II, case 007, Université Montpellier II, Place E. Bataillon, 34095 Montpellier cedex 5, France.
Get access

Abstract

Etherolysis of metal chlorides offers a versatile, simple nonhydrolyticsol-gel route to transition metal oxides. The main limitation of the processresults from the insolubility of some metal chlorides in non aqueoussolvents. The general tendency of this nonhydrolytic process is to delaycrystallization of metal oxides.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 339
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1 Brinker, C. J. and Scherer, G.W., Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing. (Academic Press, San Diego, 1990).Google Scholar
2 Livage, J., Henry, M. and Sanchez, C., Prog. Solid St. Chem, 18, 259 (1988)Google Scholar
3 Corriu, R.J.P., Leclercq, D., Lefèvre, P., Mutin, P.H. and Vioux, A., J. Non-Cryst. Solids, 146, 301 (1992); J. Mater. Chem. 2, 673 (1992); Chem. Mat.4, 961 (1992).Google Scholar
4 Burwell, R.L. Jr., Chem. Rev. 54, 615 (1954).Google Scholar
5 Hamilton, P.M., McBeth, R., Bekebrede, W. and Sisler, H.H., J. Amer. Chem. Soc. 75, 2881 (1953).Google Scholar
6 Johnson, F., in Friedel-Crafts and related reactions, volume IV Miscellaneous reactions, edited by Olah, G.A. ( J. Wiley & Sons Ltd, 1965) pp 1-109.Google Scholar
7 Menzel, W., Chem. Ber. 75 (9), 1055 (1942)Google Scholar
8 Dijkgraaf, C. and Rousseau, J.P.G., Spectrochim. Acta, 24A, 1213 (1968).Google Scholar
9 Wood, T.E., Siedle, A.R., Hill, J.R., Skarjune, R.P. and Goodbrake, C.J., Mat. Res. Symp. Proc. 180, 97 (1990).Google Scholar
10 Kamiya, K., Tanimoto, K. and Yoko, T., J. Mater. Sci. Let. 5, 402 (1986).Google Scholar
11 Aizawa, M., Nakagawa, Y., Nosaka, Y., Fujii, N. and Miyama, H., J. Non-Cryst. Solids 124, 112 (1990).Google Scholar
12 Nandi, M., Rhubright, D. and Sen, A., Inorg. Chem. 29, 3066 (1990).Google Scholar
13 Huey-Chang, W. and Kwang-Lung, L., J. Mater. Sci. 26, 2501 (1991).Google Scholar
14 Cowley, A., Fairbrother, F. and Scott, N., J. Chem. Soc. 1958. 3133.Google Scholar
15 Ko, F.I. and Maurer, S.M., J.C.S. Chem. Comm. 1990 1062.Google Scholar
16 Debsikdar, J.C., J. Non-Cryst. Solids 87, 343 (1986).Google Scholar
17 Yamaguchi, O., Tomihisa, D., Kawabata, H. and Shimizu, K., J. Am. Ceram. Soc. 70, C.94 (1987).Google Scholar