Hostname: page-component-745bb68f8f-cphqk Total loading time: 0 Render date: 2025-02-04T14:31:58.513Z Has data issue: false hasContentIssue false
  • English
  • Français

Organic-Inorganic Crystals for Optical Devices

Published online by Cambridge University Press:  10 February 2011

A. Ibanez ,
J. Zaccaro ,
P. L. Baldeck  and
R. Masse
A. Ibanez
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
J. Zaccaro
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
P. L. Baldeck
Affiliation:
Laboratoire de Spectrométrie Physique, Université Joseph Fourier, BP 87, 38402 Saint Martin d'Hères Cedex, France
R. Masse
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
Get access

Abstract

Two routes of crystal engineering and elaboration of optical materials are described. The former applied to the design of organic-inorganic crystals for quadratic nonlinear optics is supported by a strategy of deliberately engineered noncentrosymmetric structures built-up from herringbone motifs of 2-amino-5-nitropyridinium chromophore. The original crystal growth of a solid solution of a member of this family is presented and discussed. The latter is a simple and generic elaboration of stable organic nanocrystals embedded in sol-gel matrices. Several molecules and characterization techniques have been involved to demonstrate the validity of this preparation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 245
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 (a) Masse, R., Bagieu-Beucher, M., Pécaut, J., Lévy, J.P., J. Zyss, Nonlinear Optics 5, 413 (1993); (b) R. Masse, Nonlinear Optics 9, 113 (1995).Google Scholar
2 Fur, Y. Le, Bagieu-Beucher, M., Masse, R., Nicoud, J.F., Lévy, J.P., Chem. Mat. 8, 68 (1996).10.1021/cm9501731Google Scholar
3 Masse, R., J.Zyss, Molecular Engineering 1, 141 (1991).Google Scholar
4 Pécaut, J., Fur, Y. Le, Masse, R., Acta Cryst. B49, 535 (1993).10.1107/S0108768192011431Google Scholar
5 (a) Zyss, J., Masse, R., Bagieu-Beucher, M., Lévy, J.P., Adv. Mat. 5, 120 (1993). (b) O. Watanabe, T. Noritake, Y. Hirose, A. Okada, T. Kurauchi, J. Mater. Chem. 3, 1053 (1993).10.1002/adma.19930050210Google Scholar
6 Pécaut, J., Lévy, J.P. and Masse, R., J. Mater. Chem. 3, 999 (1993).10.1039/JM9930300999Google Scholar
7 Pécaut, J. and Masse, R., J. Mater. Chem. 4, 1851 (1994).10.1039/JM9940401851Google Scholar
8 Kotler, Z., Hierle, R., Josse, D., Zyss, J. and Masse, R., J. Opt. Soc. Am. B 9, 534 (1992).Google Scholar
9 Ibanez, A., Levy, J. P., Mouget, C. and Prieur, E., J. Solid State Chem 129, 22 (1997).10.1006/jssc.1996.7213Google Scholar
10 Zaccaro, J., Capelle, B. and Ibanez, A., J. Cryst. Growth 180, 229 (1997).10.1016/S0022-0248(97)00220-0Google Scholar
11 Nicoud, J.F., Masse, R., Bourgogne, C. and Evans, C., J. Mater. Chem. 7, 35 (1997).10.1039/a605836aGoogle Scholar
12 Khodja, S., Josse, D. and Zyss, J., J. Opt. Soc. Am. B 15, 751 (1998).10.1364/JOSAB.15.000751Google Scholar
13 Nalva, H.S., Kasai, H., Okada, S., Oikawa, H., Matsuda, H., Kakuta, A., Mukoh, A., and Nakanishi, H., Adv. Mater. 5, 758 (1993).Google Scholar
14 Akimov, I. A., Denisyuk, I. Yu. and Meshkov, A. M., Optics and Spectroscopy 77, 6, 858 (1994).Google Scholar
15 Spano, F.S. and Mukamel, S., Phys. Rev. A 40, 5783 (1989).10.1103/PhysRevA.40.5783Google Scholar
16 Ishihara, H. and Cho, K.. Phys. Rev. B 42, 1724 (1990).10.1103/PhysRevB.42.1724Google Scholar
17 Lefaucheux, F. and Robert, M.C. in Handbook of Crystal Growth, edited by Hurle, D.T.J. (North-Holland Amsterdam, 1994), vol 2-b, p 1271–1303.Google Scholar
18 Zaccaro, J., Bagieu-Beucher, M., Espeso, J. and Ibanez, A., J. Crystal Growth 186, 224, (1998).10.1016/S0022-0248(97)00458-2Google Scholar
19 Nakatsuka, M., Fujiioka, K., Kanabe, T. and Fujita, H., J. Cryst. Growth 171, 531 (1997).10.1016/S0022-0248(96)00675-6Google Scholar
20 He, G.S., Zieba, J., Bradshaw, J.T., , Kazmierzak and Prasad, P.N., Opt. Com. 104, 102 (1993).10.1016/0030-4018(93)90114-KGoogle Scholar
21 Bienfait, M. and Kern, R., Bull. Soc. Franq. Minér. Crist. 87, 604 (1964).Google Scholar
22 LaMer, V.K. and Dinegar, R.H., J. Am. Chem. Soc. 17, 4847 (1950).10.1021/ja01167a001Google Scholar
23 Ibanez, A., Maximov, S., Guiu, A., Chaillout, C. and Baldeck, P., submitted to Adv. Mater.Google Scholar