Hostname: page-component-745bb68f8f-grxwn Total loading time: 0 Render date: 2025-02-05T07:01:12.014Z Has data issue: false hasContentIssue false
  • English
  • Français

Magnetic Properties and Scaling Behavior in Perovskite–like La0.7(Ba1−xPbx)0.3CoO3 System

Published online by Cambridge University Press:  21 March 2011

Chiung-Hsiung Chen ,
Ting-Sheng Huang  and
Ming-Fong Tai
Chiung-Hsiung Chen
Affiliation:
Department of Physics, Chung Cheng University, 160 San-Hsing, Ming-Hsiung, Chia-Yi 621, Taiwan
Ting-Sheng Huang
Affiliation:
Department of Physics, Chung Cheng University, 160 San-Hsing, Ming-Hsiung, Chia-Yi 621, Taiwan
Ming-Fong Tai
Affiliation:
Department of Physics, Chung Cheng University, 160 San-Hsing, Ming-Hsiung, Chia-Yi 621, Taiwan
Get access

Abstract

In this study, we used x-ray diffraction patterns and dc magnetic measurements to investigate the crystallographic structure, magnetic properties and scaling behavior of the distorted perovskite La0.7(Ba1−xPbx)0.3CoO3 (0 ≤ x ≤ 0.5) system with a constant ratio of Co4+/Co3+. Samples with x = 0.0 and 0.1 were crystallized in the cubic structure with a ∼ 7.76 Å whereas samples with x ≥ 0.2 were crystallized in an orthorhombic Pbnm space group with a ∼ b ∼ 5.50 Å and c ∼ 7.85 Å. For all our samples the spin-glass-like behavior were observed in low temperature and low field ranges. The Pb2+ substitution on Ba2+ site does not significantly affect the ferromagnetic transition temperature TC, but does introduce large variation in the magnetic strength. In both the ferromagnetic and paramagnetic states the minimum values of the average effective moments provided by every Co ion occur at x = 0.3. We also observed the scaling behaviors of magnetic data in all samples. The derived values of the critical exponents (β, γ, δ) were consistent with those predicted by mean field theory and a three-dimensional Heisenberg model.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 674: Symposia T/U/V – Applications of Ferromagnetic and Optical Materials, Storage and Magnetoelectronics , 2001 , U3.8
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Coey, J. M. D., Viret, M. and Molná, S. von, Advances in Physics 48, 167 (1999).Google Scholar
2. Tai, M. F., Lee, Y. Y. and Shi, J. B., J. Mag. Magn. Mater. 209, 148 (2000).Google Scholar
3. Gayathri, N., Raychaudhuri, A. K., Tiwary, S. K., Gundakaram, R., Arulraj, A. and Rao, C. N. R., Phys. Rev. B56, 1345 (1997).Google Scholar
4. Caciuffo, R., Rinaldi, D., and , Barucca, Mira, J., Rivas, J., Señarís-Rodríguez, M. A., Radaelli, P. G., Fiorani, D. and Goodenough, J. C., Phys. Rev. B59, 1068 (1999); D. N. H. Nam, K. Jonason, P. Nordblad, N. V. Khiem and N. X. Phuc, Phys. Rev. B59, 4189 (1999).10.1103/PhysRevB.59.1068Google Scholar
5. Chen, C. H., H, T. S., Shieh, Y. L. and Tai, M. F., submitted to J. Mag. Magn. Mater. (2001).Google Scholar
6. Chen, Chiung-Hsiung, Thesis of Master Degree, National Chung Cheng University, Taiwan (July, 2001).Google Scholar
7. Chou, F. C., Belk, N. R., Kastner, M. A., and Birgeneau, R. J. and Aharony, A., Phys. Rev. Lett. 75, 2204 (1995); B. Barbara, A. P. Malozemoff and Y. Imry, Phy. Rev. Lett. 47, 1852 (1981).Google Scholar
8. Malozemoff, A. P., Barnes, S. E. and Barbara, B., Phy. Rev. Lett. 51, 1704 (1983).Google Scholar
9. Moutis, N., Panagiotopoulos, I., Pissas, M., and Niarchos, D., Phys. Rev. B59, 1129 (1999).10.1103/PhysRevB.59.1129Google Scholar