Hostname: page-component-745bb68f8f-d8cs5 Total loading time: 0 Render date: 2025-02-05T18:57:48.975Z Has data issue: false hasContentIssue false
  • English
  • Français

Iron Aluminium Silico-Phosphate Glasses Including U3O8

Published online by Cambridge University Press:  15 February 2011

Carlos J.R. Gonzalez Oliver ,
Diego O. Russo ,
Francisco C. Lovey ,
Maximina Romero  and
Jesus Ma. Rincon
Carlos J.R. Gonzalez Oliver
Affiliation:
Groups of Materials Characterization, Nuclear Materials and Physics of Metals Centro Atomico de Bariloche (CAB), S. C. de Bariloche, Argentina
Diego O. Russo
Affiliation:
Groups of Materials Characterization, Nuclear Materials and Physics of Metals Centro Atomico de Bariloche (CAB), S. C. de Bariloche, Argentina
Francisco C. Lovey
Affiliation:
Groups of Materials Characterization, Nuclear Materials and Physics of Metals Centro Atomico de Bariloche (CAB), S. C. de Bariloche, Argentina
Maximina Romero
Affiliation:
Groups of Materials Characterization, Nuclear Materials and Physics of Metals Centro Atomico de Bariloche (CAB), S. C. de Bariloche, Argentina Group/Lab of Vitreous and Ceramic Materials, Instituto E. Torroja de CC Construccion (IETcc, CSIC), Madrid, Spain
Jesus Ma. Rincon
Affiliation:
Groups of Materials Characterization, Nuclear Materials and Physics of Metals Centro Atomico de Bariloche (CAB), S. C. de Bariloche, Argentina Group/Lab of Vitreous and Ceramic Materials, Instituto E. Torroja de CC Construccion (IETcc, CSIC), Madrid, Spain
Get access

Abstract

The obtention of iron aluminium silicate- phosphate glasses including U3O8 oxide has been carried out and the study of crystalline phases formation. A serie of these original glasses have been investigated by thermal cycles at 780? C for promoting the nucleation and growth of crystalline phases of iron aluminium phosphates including U3O8 in the 5.1- 13.71 wt% range. Thermal expansion and DTA/G analysis have been carried out showing behaviour trend to crystallization of these glasses. The glass with higher uranium oxide content shows liquid phase in phase separation which change of microstructure during HREM observations. It seems produced a pulsed order- disorder processing which takes place under the electron beam. This effect first observed in TEM-HREM on phase separation droplets is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1193: Scientific Basis for Nuclear Waste Management XXXIII , 2009 , 329
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Romero, M. and Rincon, J. Ma., Bol. Soc. Esp. Ceram. Vidr. 39 (2000)1, 155–163 Google Scholar
2 Jatzen, C.M., J. Non- Crystalline Solids 84(1986)215–225.Google Scholar
3 Hidalgo, M., Rincon, J.Ma., Bol.Soc.Esp.Ceram.Vidr., 26 (1987) 4, 227–234.Google Scholar
4 Rincon, J. Ma., Caceres, J., Oliver, C. J. R. Gonzalez-, Russo, D. O., Petkova, A. and Hristov, H., J. Thermal Anal. and Cal. 56(1999) 931 - 938.Google Scholar
5 Mesko, M.G. and Day, D.E., J. Nuclear Materials 273 (1999) 27–36.Google Scholar
6 Karabulut, M., Marasinghe, G.K., Ray, C.S., Waddill, G.D. and Day, D.E.; J. Applied Physics, 87 (5) (2000) 2185–2193.Google Scholar
7 Reis, S.T., Karabulut, M. and Day, D.E.; J. Nuclear Materials 304 (2002) 87–95.Google Scholar
8 Ray, C.S., Fang, X., Karabulut, M., Marasinghe, G.K. and Day, D.E.; J. Non-Crystalline Solids 249 (1999)1–16.Google Scholar
9 Villegas, M?.A., Rincon, J.Ma., Russo, D. and Oliver, C.J.R. Gonzalez-, in: VARIREI 2005, L?Aquila, Italia, 2005, University of LAquila, RCG 6, 6 pp.Google Scholar
10 Russo, D., Gonzalez- Oliver, C.J. R., Rincon, J. Ma., J. Non- Crystalline Solids, 354 (2008) 1541–1548.Google Scholar
11 Gonzalez-Oliver, C.J. R., Russo, D., Lovey, M. and Rincon, J. Ma., HREM observations of iron phosphate glasses containing uranium oxide, XIII Annual Meeting of the SME, Bilbao, july 2007.Google Scholar
12 Yu, X., Day, D.E., Long, G.J. and Brow, R.K.; Properties and structure of sodium-iron phosphate glasses; J. Non-Crystalline Solids 215 (1997) 21–31.Google Scholar
13 Jun, S., Cha, M.R., Jung, B.H. and Kim, H.S.; J. Korean Ceramic Society 40 (11), (2003) 1127–1131.Google Scholar
14 Sturchio, N.C., Antonio, M.R. and Brannon, J.C.; Science 81 (1998) 971–973.Google Scholar
15 Marasinghe, G.K., Karabulut, M., Ray, C.S., Day, D.E., Shumsky, M.G., Yelon, W.B., Booth, C.H., Allen, P.G. and Shuh, D.K., J. Non-Crystalline Solids 222 (1997) 144–152.Google Scholar
16 ASTM Standard Test Method for Determining Chemical Durability of Nuclear Waste Glasses: The Product Consistency Test (PCT). Designation C 1285 – 94.Google Scholar
17 Russo, D.O., Rodriguez, D.S., Sterba, M., Rincon, J.Ma. Oliver, L. y C.J.R. Gonzalez; in: Jornadas Sam/ Conamet/ AAS Argentina (2001) 835–842.Google Scholar