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Published online by Cambridge University Press: 26 February 2011
X-ray diffraction and transmission electron microscopy have been used to study the morphology and defect structure of YBa2Cu3O7-δ films on [001] MgO substrates polished away from the [001] crystallographic axis towards either [010] or [110] by angles ranging from 1° to 20°. On the [010] off-axis substrates it was found that growth of the YBCO film was highly influenced by the surface normal of the substrate with only very weak alignment to the substrate [001] direction. All [010]-angled samples maintained Tc's of 86K. Angles of 1°, 2.5°, and 5° toward [010] produced films with large mosaic spread parallel to the direction of the angle, as high as 4° FWHM for the 5° sample. Critical current densities of these films remained as high as those of films grown on on-axis substrates, e.g. 4.4×107 A/cm2 at 4.2 K and zero applied field. Larger off-axis angles led to samples with reduced mosaic spread but still alignment to the surface normal, and reduced Jc's of 2×107 A/cm2 and 1×l05 A/cm2 for 10° and 20° angles, respectively. TEM investigation and in-plane x-ray examination of the 5°, 10°, and 20° samples show good in-plane texture except for the 20° sample, and increased granularity with angle. Films on substrates polished off-axis towards [110] have degraded Tc's and Jc's for all angles.