Published online by Cambridge University Press: 28 February 2011
Single-crystal films of InP have been deposited on GaAs, GaAs-coated Si, and InP substrates by metalorganic chemical vapor deposition (MOCVD). Defect-reduction schemes involving various thermal annealing recipes have been developed and characterized. Material quality has been assessed by a variety of methods including transmission electron microscopy, X-ray rocking curve analysis, low-temperature photoluminescence, lifetime measurements, Hall-effect measurements, electrochemical profiling, and Nomarski microscopy. The use of either a thermal-cycle-growth or a thermal-cycle-annealing process leads to heteroepitaxial InP film quality which is significantly improved over that of its as-grown state, with the thermal-cycle growth appearing to be the more effective technique.