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Published online by Cambridge University Press: 25 February 2011
Cordierite powders were prepared using silicon ethoxide, Mg(NO3).2.6H2O and Al (OBu)2etac (etac = ethylacetoacetate) and conditions of hydrolysis have been checked in order pure a cordierite to be obtained. D.T.A. measurements reveal a stepwise crystallization process with intermediate formation of metastable μ cordierite. Infrared studies allow to follow the evolution of the Si-O-Al network with temperature.