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13C NMR Study of Oxygen Intercalation in C60

Published online by Cambridge University Press:  15 February 2011

P. Bernier ,
I. Luk'yanchuk ,
Z. Belahmer ,
M. Ribet  and
L. Firlej
P. Bernier
Affiliation:
Groupe de Dynamique des Phases Condensées, Université de Montpellier II, Place.E.Bataillon, 34095 Montpellier Cédex 05, France
I. Luk'yanchuk
Affiliation:
Groupe de Dynamique des Phases Condensées, Université de Montpellier II, Place.E.Bataillon, 34095 Montpellier Cédex 05, France
Z. Belahmer
Affiliation:
Groupe de Dynamique des Phases Condensées, Université de Montpellier II, Place.E.Bataillon, 34095 Montpellier Cédex 05, France
M. Ribet
Affiliation:
Groupe de Dynamique des Phases Condensées, Université de Montpellier II, Place.E.Bataillon, 34095 Montpellier Cédex 05, France
L. Firlej
Affiliation:
Groupe de Dynamique des Phases Condensées, Université de Montpellier II, Place.E.Bataillon, 34095 Montpellier Cédex 05, France
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Abstract

High resolution 13C NMR has been used to investigate the properties of solid C60 after intercalation of molecular oxygen, which does not induce charge transfer with the host molecules. We show that, via the magnetic characteristics of the intercalant, information can be gained on its position and movement in the structure. In particular, molecular oxygen is found to occupy the middle of the octahedral site in the fcc structure of solid C60.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 359: Symposium G – Science and Technology of Fullerene Materials , 1994 , 499
Copyright
Copyright © Materials Research Society 1995

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References

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