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Synthesis of nanosized zirconium dioxide and its solid solutions with titanium dioxide from the CO2 supercritical fluid

Published online by Cambridge University Press:  18 January 2018

I.E. Sokolov ,
I.A. Konovalov ,
R.M. Zakalyukin ,
D.V. Golubev ,
A.S. Kumskov  and
V.V. Fomichev
I.E. Sokolov*
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technology (MIREA), Moscow 119571, Russia
I.A. Konovalov
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technology (MIREA), Moscow 119571, Russia
R.M. Zakalyukin
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technology (MIREA), Moscow 119571, Russia
D.V. Golubev
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technology (MIREA), Moscow 119571, Russia
A.S. Kumskov
Affiliation:
Institute of Crystallography named after A.V. Shubnikov, FRC Crystallography and Photonics of RAS, Moscow 119333, Russia National Research Center Kurchatov Institute, Moscow 123182, Russia
V.V. Fomichev
Affiliation:
Moscow Technological University, Institute of Fine Chemical Technology (MIREA), Moscow 119571, Russia
*
Address all correspondence to I.E. Sokolov at sokolov_iliya@yahoo.com
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Abstract

In this study, the formation solid solutions of titanium dioxide- zirconium dioxide (TiO2-ZrO2) system with the supercritical fluid method is described. The particles of solid solutions in the TiO2-ZrO2 system are spherical and form agglomerates, they are amorphous and have a size from 90 to 850 nm. The X-ray patterns of samples calcined above the temperatures of crystallization (450 °C) and phase transition (750 °C) demonstrate the decomposition of the solid solutions above the crystallization temperature and formation of phases in accordance with phase ratios in the TiO2-ZrO2 system at these temperatures. The formation solid solutions of the starting materials are observed in all region of concentrations.

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Type
Research Letters
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MRS Communications , Volume 8 , Issue 1 , March 2018 , pp. 59 - 64
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Copyright © Materials Research Society 2018 

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