Hostname: page-component-745bb68f8f-v2bm5 Total loading time: 0 Render date: 2025-01-13T20:04:31.999Z Has data issue: false hasContentIssue false
  • English
  • Français

Fluorescence properties of fluor molecules confined within nanoscale pores in a polymer matrix

Published online by Cambridge University Press:  10 June 2015

Valery N. Bliznyuk ,
Ayman F. Seliman ,
Scott M. Husson ,
George Chumanov  and
Timothy A. DeVol
Valery N. Bliznyuk*
Affiliation:
Department of Environmental Engineering and Earth Sciences, Clemson University, Clemson, South Carolina 29634, USA
Ayman F. Seliman
Affiliation:
Department of Environmental Engineering and Earth Sciences, Clemson University, Clemson, South Carolina 29634, USA
Scott M. Husson
Affiliation:
Department of Chemical and Biomolecular Engineering, Clemson University, Clemson, South Carolina 29634, USA
George Chumanov
Affiliation:
Department of Chemistry, Clemson University, Clemson, South Carolina 29634, USA
Timothy A. DeVol
Affiliation:
Department of Environmental Engineering and Earth Sciences, Clemson University, Clemson, South Carolina 29634, USA
*
Address all correspondence to Valery N. Bliznyuk atvblizny@clemson.edu
Get access

Abstract

We demonstrate that fluorescence properties of organic fluors embedded in a porous polystyrene matrix are highly sensitive to the average pore size and pore-size distribution of the matrix. The effect can be understood as two different types of confinement imposed to the fluor molecules by the matrix. First, there is geometrical confinement that restricts the fluor oscillations due to its physical contact with a pore wall. Second, there is an electronic confinement due to a local polarization of the wall material by molecular dipoles. The effects lead to a spectral shift and enhancement of the fluorescence intensity of the material.

Type
Research Letters
Information
MRS Communications , Volume 5 , Issue 2 , June 2015 , pp. 347 - 352
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Hoetzer, B., Medintz, I.L., and Hildebrandt, N.: Fluorescence in nanobiotechnology: sophisticated fluorophores for novel applications. Small 8, 2297 (2012).CrossRefGoogle Scholar
2.Stich, M.I.J., Fischer, L.H., and Wolfbeis, O.S.: Multiple fluorescent chemical sensing and imaging. Chem. Soc. Rev. 39, 3102 (2010).CrossRefGoogle ScholarPubMed
3.Schaeferling, M.: The art of fluorescence imaging with chemical sensors Angew. Chem. Int. Ed. 51, 3532 (2012).CrossRefGoogle Scholar
4.Prodi, L., Bolletta, F., Montalti, M., and Zaccheroni, N.: Luminescent chemosensors for transition metal ions. Coord. Chem. Rev. 205, 59 (2000).Google Scholar
5.Callan, J.F., de Silva, A.P., and Magri, D.C.: Luminescent sensors and switches in the early 21st century. Tetrahedron 61, 8551 (2005).Google Scholar
6.Liu, Z., He, W., and Guo, Z.: Metal coordination in photoluminescent sensing. Chem. Soc. Rev. 42, 1568 (2013).Google Scholar
7.Davydov, A.S.: Theory of Molecular Excitons (Plenum, New York, 1971).Google Scholar
8.Bücher, H. and Kuhn, H.: Schetbe aggregate formation of cyanine dyes in monolayers. Chem. Phys. Lett. 6, 183 (1970).Google Scholar
9.Wurthner, F., Kaiser, T.E., and Saha-Muller, C.R.: J-Aggregates: from serendipitous discovery to supramolecular engineering of functional dye materials. Angew. Chem. Int. Ed. 50, 3376 (2011).CrossRefGoogle ScholarPubMed
10.Márquez, F., García, H., Palomares, E., Fernández, L., and Corma, A.: Spectroscopic evidence in support of the molecular orbital confinement concept: case of anthracene incorporated in zeolites. J. Am. Chem. Soc. 122, 6520 (2000).Google Scholar
11.Cho, E.-B., Volkov, D.O., and Sokolov, I.: Ultrabright fluorescent mesoporous silica nanoparticles. Small 6, 2314 (2010).CrossRefGoogle ScholarPubMed
12.Sokolov, I. and Volkov, D.O.: Ultrabright fluorescent mesoporous silica particles. J. Mater. Chem. 20, 4247 (2010).Google Scholar
13.Márquez, F. and Sabater, M.J.: Emission frequency modulation by electronic confinement effect: Congo Red incorporated within a dendritic structure J. Phys. Chem. B 109, 16593 (2005).Google Scholar
14.Bliznyuk, V.N., Duval, C.E., Apul, O.G., Seliman, A.F., Husson, S.M., and DeVol, T.A.: High porosity scintillating polymer resins for ionizing radiation sensor applications. Polymer 56, 271 (2015).Google Scholar
15.Seliman, F., Bliznyuk, V.N., Husson, S.M., and DeVol, T.A.: Synthesis, characterization and properties of 2-(1-naphthyl)-4-viny-5-phenyloxazole and vinyl-DB18-crown-6 for low-level quantification of α and β emitters. Radiobioassay and Radiochemical Measurements Conference (RRMC), October 27–31, 2014, Knoxville, TN.Google Scholar
16.Wade, E.C., Seliman, A.F., Husson, S.M., Bliznyuk, V.N., and DeVol, T.A.: Stability of scintillating beads for ultra-trace level detection of alpha and beta emitting radionuclides. Radiobioassay and Radiochemical Measurements Conference (RRMC), October 21–25, 2013, Rohnert Park, CA.Google Scholar
17.Sperling, L.H.: Introduction to Physical Polymer Science (John Wiley & Sons, New York, 1992).Google Scholar
18.Heier, J., Steiger, R., Hany, R., and Nuesch, F.: Template synthesis of cyanine dye H-aggregates on nanostructured [6,6]-phenyl C-61-butyric acid methyl ester substrates. Phys. Chem. Chem. Phys. 13, 15714 (2011).CrossRefGoogle ScholarPubMed
19.Tian, B., Zerbi, G., and Müllen, K.: Electronic and structural properties of poly-paraphenylenevinylene from the vibrational spectra. J. Chem. Phys. 95, 3198 (1991).Google Scholar
20.Castiglioni, C., Tommasini, M., and Zerbi, G.: Raman spectroscopy of polyconjugated molecules and materials: confinement effect in one and two dimensions. Phil. Trans. R. Soc. Lond. A 362, 2425 (2004).Google Scholar
21.Czeslik, C., Kim, Y.J., and Jonas, J.: Raman spectroscopy studies of liquids confined to porous silica glasses. J. Phys. IV 10, 103 (2000).Google Scholar
Supplementary material: File

Bliznyuk supplementary material

Figures S1-S2

Download Bliznyuk supplementary material(File)
File 1.3 MB