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Hydrothermal synthesis of Mg-substituted tricalcium phosphate nanocrystals

Published online by Cambridge University Press:  28 August 2019

Wei Cui ,
Shaogang Wang ,
Rui Yang  and
Xing Zhang
Wei Cui
Affiliation:
Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning 110016, China School of Materials Sciences and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China
Shaogang Wang
Affiliation:
Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning 110016, China School of Materials Sciences and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China
Rui Yang
Affiliation:
Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning 110016, China School of Materials Sciences and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China
Xing Zhang*
Affiliation:
Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning 110016, China School of Materials Sciences and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China
*
Address all correspondence to Xing Zhang at xingzhang@imr.ac.cn
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Abstract

In this study, Mg-substituted tricalcium phosphate (Mg-TCP) nanoparticles were synthesized by hydrothermal reactions of Mg-calcite mesocrystals from echinoderm skeletons. Following the biomineralization of echinoderms, Mg-calcite powder was synthesized via the solid-state transition of Mg-amorphous calcium carbonate prepared by a wet-chemical precipitation method, which can also be used to fabricate Mg-TCP. We illustrated that Mg-calcite with a certain level of Mg substitution led to the formation of Mg-TCP through the ion-exchange reactions in the hydrothermal system. Therefore, this study provides a new pathway for the synthesis of Mg-TCP nanoparticles.

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Type
Research Letters
Information
MRS Communications , Volume 9 , Issue 3 , September 2019 , pp. 971 - 978
Copyright
Copyright © The Author(s) 2019 

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