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Small-angle neutron scattering investigation of the effect of a heat-treatment on the microstructure of porous basalt rocks

Published online by Cambridge University Press:  05 July 2018

A. Kahle ,
B. Winkler  and
A. Radulescu
A. Kahle
Affiliation:
Universität Frankfurt, Institut für Mineralogie, Abt. Kristallographie, Senckenberganlage 30, 60054 Frankfurt a.M., Germany
B. Winkler*
Affiliation:
Universität Frankfurt, Institut für Mineralogie, Abt. Kristallographie, Senckenberganlage 30, 60054 Frankfurt a.M., Germany
A. Radulescu
Affiliation:
Institut für Festkörperforschung, Forschungszentrum Jülich, 52425 Jülich, Germany
*
*E-mail: b.winkler@kristall.uni-frankfurt.de
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Abstract

Small-angle neutron scattering has been used to study the microstructure of natural porous basalt rocks. The effect of temperature on the rock microstructure has been investigated on ‘as received’ and heat-treated basalts. The magnitudes of α, the power-law scattering exponent were between 3 and 4 for the majority of the rocks, indicating a surface fractal structure between the basalt matrix and the pore space. Heat-treated basalts show higher α values, and therefore a smoother pore surface. Internal surface areas were determined for all basalts depending on the thermal history.

Keywords

neutron scatteringmicrostructureheat treatmentporous basalt

Information

Type
Research Article
Information
Mineralogical Magazine , Volume 70 , Issue 6 , December 2006 , pp. 689 - 695
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2006

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References

Allen, A.J. (1991) Time-resolved phenomena in cements, clays and porous rocks. Journal of Applied Crystallography, 24, 624–634.CrossRefGoogle Scholar
Bale, H.D. and Schmidt, P.W. (1984) Small-angle X-ray-scattering investigation of submicroscopic porosity with fractal properties. Physical Review Letters, 53, 596–599.CrossRefGoogle Scholar
Floriano, M.A., Venezia, A.M., Deganello, G., Svensson, E.C. and Root, J.H. (1994) The structure of pumice by neutron diffraction. Journal of Applied Crystallography, 27, 271–277.CrossRefGoogle Scholar
Kahle, A., Winkler, B., Radulescu, A. and Schreuer, J. (2004) Small-angle neutron scattering study of volcanic rocks. European Journal of Mineralogy, 16, 407–417.CrossRefGoogle Scholar
Knudsen, K.D., Fossum, J.O., Helgesen, G. and Haakestad, M.W. (2004) Small-angle neutron scattering from a nano-layered synthetic silicate. Physica B, 352, 247–258.CrossRefGoogle Scholar
Lucido, G., Triolo, R. and Caponetti, E. (1988) Fractal approach in petrology: Small-angle neutron scattering experiments with volcanic rocks. Physical Review B, 38, 9031–9034.CrossRefGoogle ScholarPubMed
Mildner, D.F.R. and Hall, P.L. (1986) Small-angle scattering from porous solids with fractal geometry. Journal of Physics D, 19, 1535–1545.CrossRefGoogle Scholar
Radlinski, A.P. (2006) Small angle neutron scattering and the microstructure of rocks. Pp. 363–397 in: Neutron Scattering in Earth Sciences (Wenk, H.-R., editor). Reviews in Mineralogy and Geochemistry, 63, Mineralogical Society of America, Virginia and The Geochemical Society, Washington, D.C. CrossRefGoogle Scholar
Radlinski, A.P., Boreham, C.J., Wignall, G.D. and Lin, J.-S. (1996) Microstructural evolution of source rock during hydrocarbon generation: a small-angle-scattering study. Physical Review B, 53, 14152–14160.CrossRefGoogle Scholar
Radlinski, A.P., Radlinska, E.Z., Agamalian, M., Wignall, G.D., Lindner, P. and Randl, O.G. (1999) Fractal geometry of rocks. Physical Review Letters, 82, 3078–3081.CrossRefGoogle Scholar
Radlinski, A.P., Radlinska, E.Z., Agamalian, M., Wignall, G.D., Lindner, P. and Randl, O.G. (2000) The fractal microstructure of ancient sedimentary rocks. Journal of Applied Crystallography, 33, 860–862.CrossRefGoogle Scholar
Radlinski, A.P., Mastalerz, M., Hinde, A.L., Hainbuchner, M., Rauch, H., Baron, M., Lin, J.S., Fan, L. and Thiyagarajan, P. (2004) Application of SAXS and SANS in evaluation of porosity, pore size distribution and surface area of coal. International Journal of Coal Geology, 59, 245–271.CrossRefGoogle Scholar
Schmidt, P.W. (1991) Small angle scattering studies of disordered, porous and fractal systems. Journal of Applied Crystallography, 24, 414–435.CrossRefGoogle Scholar
Sen, D., Mazumder, S. and Tarafdar, S. (2002) Pore morphology and pore surface roughening in rocks: a small-angle neutron scattering investigation. Journal of Materials Science, 37, 941–947.CrossRefGoogle Scholar
Wong, P., Howard, J. and Lin, J.-S. (1986) Surface roughening and the fractal nature of rocks. Physical Review Letters, 57, 637–640.CrossRefGoogle ScholarPubMed