The second Stiefel–Whitney class of the quadratic form trA/k(ax2) is computed, where A is a central simple algebra over a perfect field k of characteristic different from 2, a ∈ A is a fixed element, and trA/k is the reduced trace. This class is related on the one hand to the class of A in the Brauer group, and on the other hand to corestrictions of quaternion algebras over certain factors arising from E[otimes]kE, where E is a commutative étale algebra over k that depends on the semisimple part of a.