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Synthesis of oxide powders by way of a polymeric steric entrapment precursor route

Published online by Cambridge University Press:  31 January 2011

My H. Nguyen ,
Sang-Jin Lee  and
Waltraud M. Kriven
My H. Nguyen
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801
Sang-Jin Lee
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801
Waltraud M. Kriven
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801
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Abstract

A polymerized organic–inorganic complexion route is introduced for the synthesis of yttrium aluminum garnet, YAG (Y3Al5O12) and cordierite (Mg2Al4Si5O18) powders. Long-chain polymers such as polyvinyl alcohol (–[CH2–CHOH]-n or PVA) or polyethylene glycol (H[O–CH2–CH2]nOH or PEG) were used as the organic carriers for a precursor ceramic gel. Calcined powders were very porous and homogeneous in distribution of components. Experimental studies by differential thermal analysis and thermogravimetric analysis, x-ray diffraction, solid-state nuclear magnetic resonance, and Fourier transform infrared spectrometry indicated that metal-ion chelation is not the primary mechanism for obtaining molecularly homogeneous precursor powders. Water-soluble cations of mixed oxides in the PVA or PEG process were sterically entrapped in the entangled network and resulted in fine and pure, mixed oxide powders.

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Articles
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Journal of Materials Research , Volume 14 , Issue 8 , August 1999 , pp. 3417 - 3426
Copyright
Copyright © Materials Research Society 1999

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