Hostname: page-component-7dd5485656-zlgnt Total loading time: 0 Render date: 2025-10-31T09:25:46.609Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and characterization of a novel layered titanium phosphate

Published online by Cambridge University Press:  31 January 2011

Anatoly I. Bortun ,
Lyudmila Bortun ,
Abraham Clearfield ,
María A. Villa-García ,
José R. García  and
Julio Rodríguez
Anatoly I. Bortun
Affiliation:
Department of Chemistry, Texas A/M University, College Station, Texas 77843
Lyudmila Bortun
Affiliation:
Department of Chemistry, Texas A/M University, College Station, Texas 77843
Abraham Clearfield
Affiliation:
Department of Chemistry, Texas A/M University, College Station, Texas 77843
María A. Villa-García
Affiliation:
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
José R. García
Affiliation:
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
Julio Rodríguez
Affiliation:
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
Get access

Abstract

A novel metastable layered titanium phosphate has been synthesized by the treatment of layered titanates (Na2Ti3O7 and Na4Ti9O20) with 1–2 M phosphoric acid solution at 120–150 °C. Based on the data of 31P MAS NMR and IR spectroscopy, x-ray powder diffraction, and thermal and elemental analysis, the formula Ti2O3(H2PO4)2 · 2H2O was assigned to the novel compound. The layered nature of the compound was confirmed from n-alkylamine intercalation and the ion exchange behavior toward alkali, alkaline earth, and some transition metal ions.

Information

Type
Articles
Information
Journal of Materials Research , Volume 11 , Issue 10 , October 1996 , pp. 2490 - 2498
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1. Clearfield, A., Nancollas, G.H., and Blessing, R.H., in Ion Exchange and Solvent Extraction, edited by Marinsky, J.A. and Marcus, Y. (Marcel Dekker, New York, 1973), Vol. 4.Google Scholar
2. Inorganic Ion Exchange Materials, edited by A. Clearfield (CRC Press, Boca Raton, FL, 1982).Google Scholar
3. Clearfield, A., in Design of New Materials, edited by Cocke, D.L. and Clearfield, A. (Plenum Press, New York, 1987).Google Scholar
4. Alberti, G., in Recent Development in Ion Exchange, edited by Williams, P. A. and Hudson, M.J. (Elsevier, London, England, 1987).Google Scholar
5. Alberti, G. and Costantino, U., in Inclusion Compounds. Inorganic and Physical Aspects of Inclusion, edited by Atwood, J. L., Davies, J. E. D., and MacNicol, D. D. (Oxford University Press, Oxford, England, 1991), Vol. 5.Google Scholar
6. García, J. R., Llavona, R., Suárez, M., and Rodríguez, J., Trends Inorg. Chem. 3, 209 (1993).Google Scholar
7. Clearfield, A. and Smith, G. D., Inorg. Chem. 8, 431 (1969).CrossRefGoogle Scholar
8. Troup, J. M. and Clearfield, A., Inorg. Chem. 16, 3311 (1977).CrossRefGoogle Scholar
9. Bruque, S., Aranda, M. A. G., Losilla, E. R., Oliveira-Pastor, P., and Maireles-Torres, P., Inorg. Chem. 34, 893 (1995).CrossRefGoogle Scholar
10. Christensen, A. N., Andersen, E. K., Andersen, I. G. K., Alberti, G., Nielsen, M., and Lehmann, M. S., Acta Chem. Scand. 44, 865 (1990).CrossRefGoogle Scholar
11. Clayden, N. J., J. Chem. Soc., Dalton Trans., 1877 (1987).CrossRefGoogle Scholar
12. Poojary, D. M., Shpeizer, B., and Clearfield, A., J. Chem. Soc., Dalton Trans., 111 (1995).CrossRefGoogle Scholar
13. Yamanaka, S., Inorg. Chem. 15, 2811 (1976).CrossRefGoogle Scholar
14. Ortíz-Avila, C. Y. and Clearfield, A., Inorg. Chem. 24, 1173 (1985).CrossRefGoogle Scholar
15. Alberti, G., Costantino, U., Alluli, S., and Tomassini, N., J. Inorg. Nucl. Chem. 40, 1113 (1978).CrossRefGoogle Scholar
16. Dines, M.B. and DiGiacomo, P. M., Inorg. Chem. 20, 37 (1981).CrossRefGoogle Scholar
17. Clearfield, A. and Roberts, B. D., Inorg. Chem. 27, 3237 (1988).CrossRefGoogle Scholar
18. Maireles-Torres, P., Oliveira-Pastor, P., Rodríguez-Castellón, E., Jiménez-López, A., Alagna, L., and Tomlinson, A.A.G., J. Mater. Chem. 1, 319 (1991).CrossRefGoogle Scholar
19. Espina, A., Parra, J. B., García, J. R., Pajares, J. A., and Rodríguez, J., J. Mater. Chem. Phys. 35, 250 (1993).CrossRefGoogle Scholar
20. Llavona, R., Suárez, M., García, J. R., and Rodríguez, J., Inorg. Chem. 28, 37 (1991).Google Scholar
21. Yang, C. Y. and Clearfield, A., React. Polym. 5, 13 (1987).Google Scholar
22. Ortíz-Avila, C. Y., Bhardwaj, C., and Clearfield, A., Inorg. Chem. 33, 2499 (1994).CrossRefGoogle Scholar
23. Bortun, A., Jaimez, E., Llavona, R., García, J. R., and Rodríguez, J., Mater. Res. Bull. 30, 413 (1995).CrossRefGoogle Scholar
24. Spizyn, V. I. and Ippolitova, E. A., Zh. Analyt. Khim. 6, 5 (1951).Google Scholar
25. Li, Y. J. and Whittingham, M. S., Solid State Ionics 63, 391 (1993).CrossRefGoogle Scholar
26. Clearfield, A. and Lehto, J., J. Solid State Chem. 73, 98 (1988).CrossRefGoogle Scholar
27. Williams, W. J., Handbook of Anion Determination (Butterworth, London, England, 1984).Google Scholar
28. Titov, V. P., Yakubovskaya, S. V., Akulich, N. A., and Mel'nikova, R. Ya., Russ. J. Inorg. Chem. 32, 1711 (1987).Google Scholar
29. Corbridge, D. C., Crayson, M., and Griffith, E. J., in Topics in Phosphorus Chemistry (Interscience, New York, 1966), Vol. 3.Google Scholar
30. Steger, E. and Leukrot, G., Z. Anorg. Allg. Chem. 303, 169 (1960).CrossRefGoogle Scholar
31. Lasarev, A. N., Vibrational Spectra and Structure of Silicates (Consultants Bureau, New York, 1972).Google Scholar
32. Rulmont, A., Cahay, R., Liegeois-Duyckaerts, M., and Tarte, P., Eur. J. Solid State Inorg. Chem. 28, 207 (1991).Google Scholar
33. Chernorukov, N. G., Korshunov, I. A., and Zhuk, M. I., Russ. J. Inorg. Chem. 27, 1728 (1982).Google Scholar
34. Bortun, A., Strelko, V. V., Jaimez, E., García, J. R., and Rodríguez, J., Chem. Mater. 7, 249 (1995).CrossRefGoogle Scholar
35. Alberti, G., Vivani, R., Biswas, R. K., and Murcia-Mascarós, S., React. Polym. 19, 1 (1993).CrossRefGoogle Scholar
36. Menéndez, A., Bárcena, M., Jaimez, E., García, J. R., and Rodríguez, J., Chem. Mater. 5, 1078 (1993).CrossRefGoogle Scholar
37. Bortun, A. I., García, J. R., Budovitskaya, T. A., Strelko, V. V., and Rodríguez, J., Mater. Res. Bull. 31, 487 (1996).CrossRefGoogle Scholar