Hostname: page-component-cb9f654ff-p5m67 Total loading time: 0 Render date: 2025-09-09T01:38:04.629Z Has data issue: false hasContentIssue false
  • English
  • Français

Soft process for the intercalation of ammonium cations into vanadium oxide

Published online by Cambridge University Press:  31 January 2011

Michio Inagaki ,
Tomoyuki Nakamura  and
Akira Shimizu
Michio Inagaki
Affiliation:
Graduate School of Engineering, Hokkaido University, Kita-ku, Sapporo 060–8628, Japan
Tomoyuki Nakamura
Affiliation:
Graduate School of Engineering, Hokkaido University, Kita-ku, Sapporo 060–8628, Japan
Akira Shimizu
Affiliation:
Graduate School of Engineering, Hokkaido University, Kita-ku, Sapporo 060–8628, Japan
Get access

Abstract

A soft process for the intercalation of different ammonium cations into vanadium pentoxide was developed. By refluxing an aqueous solution containing ammonium , tetramethylammonium (CH3)4N+, and tetraethylammonium (C2H5)4N+ with V2O5 powders, intercalation compounds containing corresponding ammonium cations were obtained. The compound with aniline C6H5NH2 was also synthesized by the same process. The compounds with (CH3)4N+, (C2H5)4N+, and also C6H5NH2 had diffraction patterns consisting of very sharp 00l lines. The spacing for sandwiching the intercalates (the identity period), (CH3)4N+, (C2H5)4N+, and C6H5NH2, was 1.29, 1.31, and 1.39 nm, respectively.

Information

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 4 , April 1998 , pp. 896 - 900
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

1.Legendre, J-J. and Livage, J., J. Colloid Interface Sci. 94, 75 (1983).Google Scholar
2.Oka, Y., Yamamoto, N., and Yao, T., Solid State Ionics 57, 103 (1992).CrossRefGoogle Scholar
3.Miura, T., Sugiura, E., Kishi, T., and Nagai, T., Denki Kagaku 56, 413 (1988).Google Scholar
4.Badot, J. C., Binet, L., Baffier, N., Morineau, R., and Lamer, A. Fourrier, Solid State Ionics 53–56, 343 (1992).CrossRefGoogle Scholar
5.Yao, T., Oka, Y., and Yamamoto, N., J. Mater. Chem. 2, 331 (1992).CrossRefGoogle Scholar
6.Aldebert, P., Baffier, N., Legendre, J. J., and Livage, J., Rev. Chim. Min. 19, 485 (1982).Google Scholar
7.Bouhaouss, A. and Aldebert, P., Mater. Res. Bull. 18, 1247 (1983).Google Scholar
8.Watanabe, T., Shimizu, A., and Inagaki, M., J. Mater. Chem. 5, 753 (1995).Google Scholar
9.Inagaki, M., Watanabe, T., and Shimizu, A., Solid State Ionics 86–88, 853 (1996).Google Scholar
10.Leroux, F., Koene, B. E., and Nazar, L. F., J. Electrochem. Soc. 143, L181 (1996).CrossRefGoogle Scholar
11.Miura, T., Kunihiro, S., Muranushi, Y., and Kishi, T., Denki Kagaku 57, 393 (1989).CrossRefGoogle Scholar