Hostname: page-component-cb9f654ff-lqqdg Total loading time: 0 Render date: 2025-08-27T03:52:20.277Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation, properties, and photodoping behavior of GeS2-, Ga2S3-, and Sb2S3-based glasses with excess sulfur and CsCl

Published online by Cambridge University Press:  15 July 2019

Kayo Hosoya ,
Yomei Tokuda ,
Arifumi Okada ,
Takashi Wakasugi  and
Kohei Kadono
Kayo Hosoya
Affiliation:
Graduate School of Science and Technology, Kyoto Institute of Technology, Kyoto 606-8585, Japan
Yomei Tokuda
Affiliation:
Department of Education, Shiga University, Otsu-city, Shiga 520-0862, Japan
Arifumi Okada
Affiliation:
Faculty of Materials Science and Engineering, Kyoto Institute of Technology, Kyoto 606-8585, Japan
Takashi Wakasugi
Affiliation:
Faculty of Materials Science and Engineering, Kyoto Institute of Technology, Kyoto 606-8585, Japan
Kohei Kadono*
Affiliation:
Faculty of Materials Science and Engineering, Kyoto Institute of Technology, Kyoto 606-8585, Japan
*
a)Address all correspondence to this author. e-mail: kadono@kit.ac.jp
Get access

Abstract

Glasses were prepared in systems based on two stoichiometric sulfides that were selected from Ga2S3, GeS2, and Sb2S3, with the incorporation of excess sulfur and CsCl. We investigated the fundamental properties, including glass transition, density, and optical absorption, and their variations with the incorporation of excess sulfur and CsCl into the pseudo two-component sulfide glasses. The incorporation of CsCl into the GeS2–Sb2S3 glasses shifted the absorption edge at the short-wavelength side to the long-wavelength direction, particularly for glasses with more amount of GeS2 than SbS3/2. In both cases of CsCl incorporation into the Ga2S3–GeS2 glass and Ga2S3–Sb2S3 glass systems, the absorption edges shifted to the short-wavelength direction regardless of the compositions. Ag photodoping behaviors were investigated for the bulk sulfide glasses with excess sulfur and CsCl. The results are discussed based on the diffusion of silver in the glass network that is modified by the incorporation.

Keywords

amorphousAgS

Information

Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 16 , 28 August 2019 , pp. 2747 - 2756
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Sanghera, J., Shaw, B., and Aggarwal, I.: Applications of chalcogenide glass optical fibers. C. R. Chim. 5, 873 (2002).CrossRefGoogle Scholar
Bureau, B., Zhang, X.H., Smektala, F., Adam, J-L., Troles, J., Ma, H-l., Boussard-Plèdel, C., Lucas, J., Lucas, P., Coq, D.L., Riley, M.R., and Simmons, J.H.: Recent advances in chalcogenide glasses. J. Non-Cryst. Solids 345&346, 276 (2004).CrossRefGoogle Scholar
Zhang, X.H., Bureau, B., Lucas, P., Boussard-Pledel, C., and Lucas, J.: Glasses for seeing beyond visible. Chem. Eur. J. 14, 432 (2008).CrossRefGoogle ScholarPubMed
Le Toullec, M., Christensen, P.S., and Lucas, J.: A new family of vitreous materials: The cesium aluminum or gallium thiohalide glasses. Mat. Res. Bull. 22, 1517 (1987).CrossRefGoogle Scholar
Sanghera, J.S., Heo, J., and Mackenzie, J.D.: Chalcohalide glasses. J. Non-Cryst. Solids 103, 155 (1988), and references cited in this review.CrossRefGoogle Scholar
Tver’yanovich, Y.S., Nedoshovenko, E.G., Aleksandrov, V.V., Turkina, E.Y., Tver’yanovich, A.S., and Sokolov, I.A.: Chalcogenide glasses containing metal chlorides. Glass Phys. Chem. 22, 9 (1996).Google Scholar
Calvez, L., Ma, H.L., Lucas, J., and Zhang, X.H.: Selenium-based glasses and glass ceramics transmitting light from the visible to the far-IR. Adv. Mater. 9, 129 (2007).CrossRefGoogle Scholar
Ledemi, Y., Amraouri, M.E., and Messaddeq, Y.: Transmission enhancement in chalco-halide glasses for multiband applications. Opt. Mat. Exp. 4, 1725 (2014).CrossRefGoogle Scholar
Bréhault, A., Calvez, L., Adam, P., Rollin, J., Cathelinaud, M., Fan, B., Merdrignac-Conanec, O., Pain, T., and Zhang, X.H.: Moldable multispectral glasses in GeS2–Ga2S3–CsCl system transparent from the visible up to the thermal infrared regions. J. Non-Cryst. Solid 431, 25 (2016).CrossRefGoogle Scholar
Kuroda, K., Okumura, K., Fujiwara, R., Wakasugi, T., and Kadono, K.: Glass formation, properties, and structure of the glasses based on GeS2–Sb2S3–CsX (X = Cl, Br, I). Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B 58, 21 (2017).Google Scholar
Ashida, T., Wakasugi, T., Okada, A., and Kadono, K.: Glass formation and properties of the glasses based on As- and Ge-free sulfide systems for infrared transmitting materials. Chem. Lett. 45, 63 (2016).CrossRefGoogle Scholar
Qiu, J., Yang, A., Zhang, M., Li, L., Zhang, B., Tang, D., and Yang, Z.: Ga2S3–Sb2S3–CsI chalcohalide glasses for mid-infrared applications. J. Am. Ceram. Soc. 100, 5107 (2017).CrossRefGoogle Scholar
Zhang, M., Yang, Z., Zhao, H., Yang, A., Li, L., and Tao, H.: Glass forming and properties of Ga2S3–Sb2S3–CsCl chalcohalide system. J. Alloys Comp. 722, 166 (2017).CrossRefGoogle Scholar
Ashida, T., Okada, A., Wakasugi, T., and Kadono, K.: Glass formation and properties of glasses based on Ga2S3–Sb2S3 systems incorporated with CsX (X = Cl, Br, I) and AgCl. J. Cer. Soc. Jpn. 126, 452 (2018).CrossRefGoogle Scholar
Frederikse, H.P.R.: Section 12 properties of solids, polarizabilities of atoms and ions in solids. In CRC Handbook of Chemistry and Physics, 90th ed. by D.R. Lide and W.M. “Mickey” Haynes (CRC Press, Boca Raton, 2009); pp. 13–14.Google Scholar
Tanaka, K. and Shimakawa, K.: Light-induced phenomena. In Amorphous Chalcogenide Semiconductors and Related Materials (Springer, New York, 2011); ch. 6.CrossRefGoogle Scholar
Tanaka, K.: Photodoping of Ag in Ag–As–S glasses. J. Non-Cryst. Solids 170, 27 (1994); ch.6, pp. 141–193.CrossRefGoogle Scholar
Kitagawa, R., Takebe, H., and Kuwabara, M.: Behavior of Ag photodoping in sulfide bulk glasses. J. Non-Cryst. Solids 352, 2643 (2006).CrossRefGoogle Scholar
Terakado, N. and Tanaka, K.: Ag-photodoping in nano-structured GeO2–GeS2 glasses. Phys. St. Sol. C 6, S75 (2009).Google Scholar
Kadono, K., Fujiwara, R., Takahiro, K., and Wakasugi, T.: Effect of composition on photodoping behaviors in bulk Ge–Sb–S glasses. Phys. St. Sol. C 9, 2570 (2012).Google Scholar
Kawamoto, Y. and Tsuchihachi, S.: The properties and structure of glasses in the system As2S3–Sb2S3. J. Ceram. Assoc. Jpn. 77, 328 (1969).CrossRefGoogle Scholar
Higuchi, H., Kanno, R., Kawamoto, Y., Takahashi, M., and Kadono, K.: Local structures of Er3+ containing Ga2S3–GeS2–La2S3 glass. Phys. Chem. Glasses 40, 122 (1999).Google Scholar
Song, J.H., Choi, Y.G., and Heo, J.: Ge and Ga K-edge EXAFS analyses on the structure of Ge–Ga–S–CsBr glasses. J. Non-Crys. Solid 352, 423 (2006).CrossRefGoogle Scholar
Kobliska, R.J. and Solin, S.A.: Temperature dependence of the Raman spectrum and the depolarization spectrum of amorphous As2S3. Phys. Rev. B 8, 756 (1973).CrossRefGoogle Scholar
Lucovsky, G., Galeener, F.L., Keezer, R.C., Geils, R.H., and Six, H.A.: Structural interpretation of the infrared and Raman spectra of glasses in the alloy system Ge1−xSx. Phys. Rev. B 10, 5134 (1974).CrossRefGoogle Scholar
Frumarová, B., Němec, P., Frumar, M., Oswald, J., and Vlček, M.: Synthesis and optical properties of the Ge–Sb–S:PrCl3 glass system. J. Non-Cryst. Solids, 256&257, 266 (1999).CrossRefGoogle Scholar
Watanabe, I., Noguchi, S., and Shimizu, T.: Study on local structure in amorphous Sb–S films by Raman scattering. J. Non-Cryst. Solids 58, 35 (1983).CrossRefGoogle Scholar
Heo, J., Yoon, J.M., and Ryou, S-Y.: Raman spectroscopic analysis on the solubility mechanism of La3+ in GeS2–Ga2S3 glasses. J. Non-Cryst. Solids 238, 115 (1998).CrossRefGoogle Scholar
Koudelka, L., Frumar, M., and Pisárčik, M.: Raman spectra of Ge–Sb–S system glasses in the S-rich region. J. Non-Cryst. Solids 41, 171 (1980).CrossRefGoogle Scholar
Kawaguchi, T. and Masui, K.: Analysis of change in optical transmission spectra resulting from Ag photodoping in chalcogenide film. Jpn J. Appl. Phys. 26, 15 (1987).CrossRefGoogle Scholar
Kawaguchi, T. and Maruno, S.: Composition dependence of Ag photodoping into amorphous Ge–S films. J. Appl. Phys. 71, 2195 (1992).CrossRefGoogle Scholar
Ichikawa, M., Wakasugi, T., and Kadono, K.: Glass formation, physico-chemical properties, and structure of glasses based on Ga2S3–GeS2–Sb2S3 system. J. Non-Cryst. Solids 356, 2235 (2010).CrossRefGoogle Scholar
Molar volumes of crystals were calculated from the data of crystal structures in X-ray diffraction data, PDF #71-0007, #42-1393, and 73-0390 for GeS2, Sb2S3, and CsCl, respectively.Google Scholar
Owen, A.E., Firth, A.P., and Ewen, P.J.S.: Photo-induced structural and physico-chemical changes in amorphous chalcogenide semiconductors. Philos. Mag. B52, 347 (1985).CrossRefGoogle Scholar
Tanaka, K.: Photoelectronic process of photodoping in the Ag/As–S system. J. Appl. Phys. 70, 7397 (1991).CrossRefGoogle Scholar
Tanaka, K. and Sanjoh, H.: Photodoping dynamics in the Ag/As–S system. J. Appl. Phys. 74, 1106 (1993).CrossRefGoogle Scholar
Ohko, Y., Tatsuma, T., Fujii, T., Naoi, K., Niwa, C., Kubota, Y., and Fujishima, A.: Multicolour photochromism of TiO2 films loaded with silver nanoparticles. Nature Mat 2, 29 (2003).CrossRefGoogle ScholarPubMed
Kawahara, K., Suzuki, K., Ohko, Y., and Tatsuma, T.: Electron transport in silver-semiconductor nanocomposite films exhibiting multicolor photochromism. Phys. Chem. Chem. Phys. 7, 3851 (2005).CrossRefGoogle ScholarPubMed
Qiao, Q., Zhang, X., Lu, Z., Wang, L., Liu, Y., Zhu, X., and Li, J.: Formation of holographic fringes on photochromic Ag/TiO2 nanocomposite films. Appl. Phys. Lett. 94, 074104 (2009).CrossRefGoogle Scholar
Han, R., Zhan, X., Wang, L., Dai, R., and Liu, Y.: Size-dependent photochromism-based holographic storage of Ag/TiO2 nanocomposite film. Appl. Phys. Lett. 98, 221905 (2011).CrossRefGoogle Scholar
Supplementary material: File

Hosoya et al. supplementary material

Figures S1-S9

Download Hosoya et al. supplementary material(File)
File 1.1 MB