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Preparation and Microstructure Characterization of Anodic Spark Deposited Barium Titanate Conversion Layers

Published online by Cambridge University Press:  31 January 2011

J. Schreckenbach ,
F. Schlottig ,
G. Marx ,
W. M. Kriven ,
O. O. Popoola ,
M. H. Jilavi  and
S. D. Brown
J. Schreckenbach
Affiliation:
Institut für Chemie, Technische Universität Chemnitz, D-09107, Chemnitz, Germany
F. Schlottig
Affiliation:
Institut für Chemie, Technische Universität Chemnitz, D-09107, Chemnitz, Germany
G. Marx
Affiliation:
Institut für Chemie, Technische Universität Chemnitz, D-09107, Chemnitz, Germany
W. M. Kriven
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, Illinois 61801
O. O. Popoola
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, Illinois 61801
M. H. Jilavi
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, Illinois 61801
S. D. Brown
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana–Champaign, Urbana, Illinois 61801
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Abstract

Anodic spark deposition (ASD) is an advanced plasma-electrochemical coating process to prepare polycrystalline, ceramic-like conversion coatings on metal surfaces. As an example, polycrystalline barium titanate (BaTiO3) phases have been prepared by the anodic conversion of metal substrate and the metal ions in the electrolyte. By a combination of various characterization techniques, the configuration of the coating was elucidated. On the metal substrate a thin (~50 nm) passivating amorphous film of titania (TiO2) first forms, which subsequently changes to anatase and rutile structures. With increasing anodic potentials, a plasma-chemical conversion reaction starts, leading to the heterogeneous formation of BaTiO3 layers of 2–10 μm thickness. The results of this study lead to the formulation of a model describing a polycrystalline and inhomogeneous layer configuration.

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Articles
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Journal of Materials Research , Volume 14 , Issue 4 , April 1999 , pp. 1437 - 1443
Copyright
Copyright © Materials Research Society 1999

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