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Preparation and characterization of NH4Bi3F10

Published online by Cambridge University Press:  31 January 2011

D. Niznansky  and
J.L. Rehspringer
D. Niznansky*
Affiliation:
E.H.I.C.S.-I.P.C.M.S., Groupe des Materiaux Inorganiques, 1, rue Blaise Pascal, 67 008 Strasbourg Cedex, France
J.L. Rehspringer
Affiliation:
E.H.I.C.S.-I.P.C.M.S., Groupe des Materiaux Inorganiques, 1, rue Blaise Pascal, 67 008 Strasbourg Cedex, France
*
a)Permanent address: Institute of Inorganic Chemistry, Rez near Prague, Czechoslovakia.
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Abstract

A new NH4Bi3F10 compound was prepared, which results from a reaction between Bi2O3 and NH4F in an argon stationary atmosphere. It has a cubic fluorite-related structure isotypic with KBi3F10 with space group Fm3m (a = 11.974 Å). Further heating leads to decomposition to BiF3. IR spectra at different temperatures show the disappearance of NH4 group characteristic vibrations. Indexed x-ray diffraction pattern and IR spectra at different decomposition temperatures are given.

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Type
Articles
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Journal of Materials Research , Volume 7 , Issue 9 , September 1992 , pp. 2511 - 2513
Copyright
Copyright © Materials Research Society 1992

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