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Plasmonic Ag@SiO2 core/shell structure modified g-C3N4 with enhanced visible light photocatalytic activity

Published online by Cambridge University Press:  29 July 2013

Jie Chen ,
Shaohua Shen ,
Penghui Guo ,
Meng Wang ,
Jinzhan Su ,
Daming Zhao  and
Liejin Guo
Jie Chen
Affiliation:
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Shaanxi 710049, China
Shaohua Shen*
Affiliation:
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Shaanxi 710049, China
Penghui Guo*
Affiliation:
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Shaanxi 710049, China
Meng Wang
Affiliation:
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Shaanxi 710049, China
Jinzhan Su
Affiliation:
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Shaanxi 710049, China
Daming Zhao
Affiliation:
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Shaanxi 710049, China
Liejin Guo*
Affiliation:
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Shaanxi 710049, China
*
a) Address all correspondence to these authors. e-mail: shshen_xjtu@mail.xjtu.edu.cn
b) e-mail: lj-guo@mail.xjtu.edu.cn
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Abstract

High rate of charge carrier recombination is a critical factor limiting the photocatalytic activity of g-C3N4. In this contribution, we demonstrate that this issue can be alleviated by constructing a plasmonic photocatalyst with tailored plasmonic-metal nanostructures, i.e., core–shell-typed Ag@SiO2 nanoparticles. Compared with pure g-C3N4, the photocatalytic hydrogen production activity was enhanced by 63% for Ag@SiO2/g-C3N4. As analysis from the photoluminescence results, the enhancement could be attributed to that plasmonic nanostructures favored the separation of electron–hole pairs in the semiconductor due to localized surface plasmons resonance effect. It was found that the silica shell between the Ag nanoparticles and g-C3N4 was essential for the better photocatalytic activity of Ag@SiO2/g-C3N4 than that of Ag/g-C3N4 by limiting the energy-loss Förster energy transfer process.

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Articles
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Journal of Materials Research , Volume 29 , Issue 1: Focus Issue: Synthesis of Nanostructured Functional Oxides , 14 January 2014 , pp. 64 - 70
Copyright
Copyright © Materials Research Society 2013 

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References

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