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MASS-NMR structural analysis of barium aluminofluorophosphate glasses with and without nitridation

Published online by Cambridge University Press:  31 January 2011

Joseph P. Fletcher ,
Subhash H. Risbud  and
R. James Kirkpatrick
Joseph P. Fletcher
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, Arizona 85721
Subhash H. Risbud
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, Arizona 85721
R. James Kirkpatrick
Affiliation:
School of Chemical Sciences and Department of Geology, University of Illinois, Urbana, Illinois 61801
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Abstract

The local structure of barium-aluminofluorophosphate (Ba–Al–P–O–F) glasses was investigated using high resolution magic-angle sample spinning nuclear magnetic resonance (MASS-NMR) spectroscopy. The 27Al spectra show three different aluminum environments [Al(4), Al(5), and Al(6)] in these glasses. Changes were observed due to the addition of fluorine and nitrogen. 31P results indicate only one type of phosphorus environment which shifts with fluorine additions. The 19F spectra suggest that fluorine has both Ba and Al as nearest neighbors.

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Journal of Materials Research , Volume 5 , Issue 4 , April 1990 , pp. 835 - 840
Copyright
Copyright © Materials Research Society 1990

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