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Low temperature synthesis of ultrafine Pb(Zr, Ti)O3 powder by sol-gel combustion

Published online by Cambridge University Press:  31 January 2011

J. Schäfer ,
W. Sigmund ,
S. Roy  and
F. Aldinger
J. Schäfer
Affiliation:
Max-Planck-Institut für Metallforschung, Pulvermetallurgisches Laboratorium und Institut für Nichtmetallische Anorganische Materialien, Universität Stuttgart, Heisenbergstrasse 5, 70569 Stuttgart, Germany
W. Sigmund
Affiliation:
Max-Planck-Institut für Metallforschung, Pulvermetallurgisches Laboratorium und Institut für Nichtmetallische Anorganische Materialien, Universität Stuttgart, Heisenbergstrasse 5, 70569 Stuttgart, Germany
S. Roy
Affiliation:
Max-Planck-Institut für Metallforschung, Pulvermetallurgisches Laboratorium und Institut für Nichtmetallische Anorganische Materialien, Universität Stuttgart, Heisenbergstrasse 5, 70569 Stuttgart, Germany
F. Aldinger
Affiliation:
Max-Planck-Institut für Metallforschung, Pulvermetallurgisches Laboratorium und Institut für Nichtmetallische Anorganische Materialien, Universität Stuttgart, Heisenbergstrasse 5, 70569 Stuttgart, Germany
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Abstract

Lead zirconate titanate powders are derived from a novel aqueous-based citrate-nitrate/oxynitrate sol-gel combustion process. Aqueous solutions of metal nitrates or oxynitrates are transformed into gels with citric acid under heating. The received gels undergo a self-propagating combustion reaction on heating to 180 °C and subsequently yield voluminous ashes. These ashes form single phase perovskite Pb(Zr0.53Ti0.47)O3 powder with a specific surface area of 8 m2/g upon calcination at 550 °C. The ashes show a homogeneous distribution of lead, zirconium, and titanium ions which guarantees short diffusion paths in solid state formation of PZT perovskite. The redox behavior of the gels was studied with the help of DTA experiments. Powders are characterized in terms of XRD, SEM, and EDX analysis.

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Articles
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Journal of Materials Research , Volume 12 , Issue 10 , October 1997 , pp. 2518 - 2521
Copyright
Copyright © Materials Research Society 1997

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