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Chemical Attachment of Organic Functional Groups to Single-walled Carbon Nanotube Material

Published online by Cambridge University Press:  31 January 2011

Y. Chen ,
R. C. Haddon ,
S. Fang ,
A. M. Rao ,
P. C. Eklund ,
W. H. Lee ,
E. C. Dickey ,
E. A. Grulke ,
J. C. Pendergrass  and
A. Chavan
...Show all authors
Y. Chen
Affiliation:
Departments of Chemistry and Physics, University of Kentucky, Lexington, Kentucky 40506–0055
R. C. Haddon
Affiliation:
Departments of Chemistry and Physics, University of Kentucky, Lexington, Kentucky 40506–0055
S. Fang
Affiliation:
Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506–0055
A. M. Rao
Affiliation:
Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506–0055
P. C. Eklund
Affiliation:
Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506–0055
W. H. Lee
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky 40506–0055
E. C. Dickey
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky 40506–0055
E. A. Grulke
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky 40506–0055
J. C. Pendergrass
Affiliation:
Departments of Chemistry and Pharmacy, University of Kentucky, Lexington, Kentucky 40506–0055
A. Chavan
Affiliation:
Departments of Chemistry and Pharmacy, University of Kentucky, Lexington, Kentucky 40506–0055
B. E. Haley
Affiliation:
Departments of Chemistry and Pharmacy, University of Kentucky, Lexington, Kentucky 40506–0055
R. E. Smalley
Affiliation:
Center for Nanoscale Science and Technology, Rice Quantum Institute and Departments of Chemistry and Physics, Rice University, Houston, Texas 77251
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Abstract

We have subjected single-walled carbon nanotube materials (SWNTM's) to a variety of organic functionalization reactions. These reactions include radioactive photolabeling studies using diradical and nitrene sources, and treatment with dichlorocarbene and Birch reduction conditions. All of the reactions provide evidence for chemical attachment to the SWNTM's, but because of the impure nature of the staring materials, we are unable to ascertain the site of reaction. In the case of dichlorocarbene we are able to show the presence of chlorine in the SWNT bundles, but as a result of the large amount of amorphous carbon that is attached to the tube walls, we cannot distinguish between attachment of dichlorocarbene to the walls of the SWNT's and reaction with the amorphous carbon.

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Articles
Information
Journal of Materials Research , Volume 13 , Issue 9 , September 1998 , pp. 2423 - 2431
Copyright
Copyright © Materials Research Society 1998

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