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Bulk amorphous Pd–Ni–Fe–P alloys: Preparation and characterization

Published online by Cambridge University Press:  31 January 2011

T. D. Shen ,
Y. He  and
R. B. Schwarz
T. D. Shen
Affiliation:
Materials Science and Technology Division, MS K765, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
Y. He
Affiliation:
Materials Science and Technology Division, MS K765, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
R. B. Schwarz
Affiliation:
Materials Science and Technology Division, MS K765, Los Alamos National Laboratory, Los Alamos, New Mexico 87545
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Abstract

Bulk amorphous alloys of PdxNiyFe80−x−yP20 (25 ≤ x ≤ 60, 20 ≤ y ≤ 55, x + y ≥ 60) were prepared by a flux-melting and water-quenching method. Seven-mm diameter glassy rods of Pd40Ni40−xFexP20 (0 ≤ x ≤ 20) were studied in greater detail. For these alloys, the difference between the crystallization and glass transition temperatures ranges from 102 K for x = 0 to 53 K for x = 20. In this composition range, the reduced glass transition temperature, Trg, ranges from 0.66 to 0.57. The change in density upon crystallization ranges from 0.24 ± 0.04% for x = 0 to 1.33 ± 0.24% for x = 10. The partial molar volume of Fe in amorphous Pd40Ni40−xFexP20 alloys is significantly larger than the molar volume of (metastable) fcc Fe. This, as well as a comparison with the molar volumes of crystalline compounds, suggests chemically selective Fe–Pd bonding in these glasses.

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Articles
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Journal of Materials Research , Volume 14 , Issue 5 , May 1999 , pp. 2107 - 2115
Copyright
Copyright © Materials Research Society 1999

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