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Synthesis of nanoparticles, nanorods, and mesoporous SnO2 as anode materials for lithium-ion batteries

Published online by Cambridge University Press:  04 March 2014

Zheng Jiao ,
Dandan Chen ,
Yong Jiang ,
Haijiao Zhang ,
Xuetao Ling ,
Hua Zhuang ,
Ling Su ,
Hui Cao ,
Ming Hou  and
Bing Zhao
Zheng Jiao
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Dandan Chen
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China; and Shanghai Aerospace Power Technology Company Limited, Shanghai 201615, People's Republic of China
Yong Jiang*
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Haijiao Zhang
Affiliation:
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, People's Republic of China
Xuetao Ling
Affiliation:
Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, People's Republic of China
Hua Zhuang
Affiliation:
Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, People's Republic of China
Ling Su
Affiliation:
Shanghai Aerospace Power Technology Company Limited, Shanghai 201615, People's Republic of China
Hui Cao
Affiliation:
Shanghai Aerospace Power Technology Company Limited, Shanghai 201615, People's Republic of China
Ming Hou
Affiliation:
Shanghai Aerospace Power Technology Company Limited, Shanghai 201615, People's Republic of China
Bing Zhao*
Affiliation:
Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, People's Republic of China
*
a) Address all correspondence to these authors. e-mail: jiangyong@shu.edu.cn
b) e-mail: bzhao@shu.edu.cn
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Abstract

The mesoporous and nanorods SnO2 are synthesized by controlling the state of SnCl2·2H2O precursor with SBA-15 as hard template, and the possible formation mechanisms at different assembling modes inside the ordered mesoporous silica templates are proposed. In addition, SnO2 nanoparticles are synthesized by hydrolysis depositing method. The electrochemical tests of as-prepared samples indicate that the reticular stacking structure of the nanorods would limit the Li+ ions to intercalate, but the effect of volume expansion in this case upon cycling is insignificant. The mesostructure SnO2 tends to be stable after partial structural collapse at first few cycles. And the Li+ ions can readily intercalate and de-intercalate into/from its ordered channels structure, which provides a high capacity and an improved cycle property. Although SnO2 nanoparticles deliver high capacity at an early stage, the agglomeration may induce the capacity to drop rapidly after a certain number of cycles.

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Type
Articles
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Journal of Materials Research , Volume 29 , Issue 5 , 14 March 2014 , pp. 609 - 616
Copyright
Copyright © Materials Research Society 2014 

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References

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