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Intercalation of cyclic amines in α–hafnium bis(hydrogen phosphate) monohydrate

Published online by Cambridge University Press:  31 January 2011

M. Suáarez ,
R. Llavona ,
M. L. Rodríguez ,
L. M. Barcina ,
A. Anillo  and
J. Rodríguez
M. Suáarez
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
R. Llavona
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
M. L. Rodríguez
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
L. M. Barcina
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
A. Anillo
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
J. Rodríguez*
Affiliation:
Departamento de Quimica Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain
*
a) Author correspondence to this addressed.
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Abstract

The intercalation in vapor phase of cyclic amines (aniline, benzylamine, cyclohexylamine, piperidine, and pyridine) in α–hafnium bis(hydrogen phosphate) monohydrate (α–HfP) has been investigated. Elemental and thermal analysis lead to the establishment of the intercalate composition. The general formula is x[Hf(HPO4)2 · y amine H2O] (1 - x) α–HfP where y = 2, 1 and x ≤ 1. When y = 1 (piperidine and pyridine) the amines form a monomolecular layer. When y = 2 (aniline, benzylamine, and cyclohexylamine) the arrangement is bimolecular. The results are compared to those described for α–ZrP.

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Articles
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Journal of Materials Research , Volume 13 , Issue 5 , May 1998 , pp. 1218 - 1224
Copyright
Copyright © Materials Research Society 1998

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