Published online by Cambridge University Press: 10 October 2014
A large eddy simulation (LES) is used to estimate a reliable horizontal turbulent diffusion coefficient,   $\def \xmlpi #1{}\def \mathsfbi #1{\boldsymbol {\mathsf {#1}}}\let \le =\leqslant \let \leq =\leqslant \let \ge =\geqslant \let \geq =\geqslant \def \Pr {\mathit {Pr}}\def \Fr {\mathit {Fr}}\def \Rey {\mathit {Re}}K_{{h}}$ , in a convective mixed layer (CML). The introduction of a passive scalar field with a fixed horizontal gradient at a given time enables
 $\def \xmlpi #1{}\def \mathsfbi #1{\boldsymbol {\mathsf {#1}}}\let \le =\leqslant \let \leq =\leqslant \let \ge =\geqslant \let \geq =\geqslant \def \Pr {\mathit {Pr}}\def \Fr {\mathit {Fr}}\def \Rey {\mathit {Re}}K_{{h}}$ , in a convective mixed layer (CML). The introduction of a passive scalar field with a fixed horizontal gradient at a given time enables   $K_{{h}}$  estimation as a function of height, based on the simulated turbulent horizontal scalar flux. Here
 $K_{{h}}$  estimation as a function of height, based on the simulated turbulent horizontal scalar flux. Here   $K_{{h}}$  is found to be of the order of
 $K_{{h}}$  is found to be of the order of   $100\ {\mathrm{m}}^2\ {\mathrm{s}}^{-1}$  for a typical terrestrial atmospheric CML. It is shown to scale by the product of the CML convective velocity,
 $100\ {\mathrm{m}}^2\ {\mathrm{s}}^{-1}$  for a typical terrestrial atmospheric CML. It is shown to scale by the product of the CML convective velocity,   $w_{*}$ , and its depth,
 $w_{*}$ , and its depth,   $h$ . Here
 $h$ . Here   $K_{{h}}$  is characterized by a vertical profile in the CML: it is large near both the bottom and top of the CML, where horizontal flows associated with convection are large. The equation pertaining to the temporal rate of change of a horizontal scalar flux suggests that
 $K_{{h}}$  is characterized by a vertical profile in the CML: it is large near both the bottom and top of the CML, where horizontal flows associated with convection are large. The equation pertaining to the temporal rate of change of a horizontal scalar flux suggests that   $K_{{h}}$  is determined by a balance between production and pressure correlation at a fully developed stage. Pressure correlation near the bottom of the CML is localized in convergence zones near the boundaries of convective cells and becomes large within an eddy turnover time,
 $K_{{h}}$  is determined by a balance between production and pressure correlation at a fully developed stage. Pressure correlation near the bottom of the CML is localized in convergence zones near the boundaries of convective cells and becomes large within an eddy turnover time,   $h/w_{*}$ , after the introduction of the passive scalar field.
 $h/w_{*}$ , after the introduction of the passive scalar field.