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Water-adsorption properties of Xiazijie montmorillonite intercalated with polyamine

Published online by Cambridge University Press:  02 January 2018

Shifeng Zhang ,
Zhengsong Qiu  and
Weian Huang
Shifeng Zhang
Affiliation:
School of Petroleum Engineering, China University of Petroleum (Huadong), Qingdao 266580, China
Zhengsong Qiu*
Affiliation:
School of Petroleum Engineering, China University of Petroleum (Huadong), Qingdao 266580, China
Weian Huang
Affiliation:
School of Petroleum Engineering, China University of Petroleum (Huadong), Qingdao 266580, China
*
E-mail:upczhang87@163.com
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Abstract

Polyamine is a novel inhibitor applied to water-based drilling fluids in order to reduce hydration of clays, especiallymontmorillonite (MT). In the present study, thewater-adsorption properties of montmorillonite intercalated with polyamine were characterized by X-ray diffraction (XRD), diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) and adsorption isotherm tests using water, benzene and heptane. According to the XRD, DRIFT and water-adsorption test results, polyamine (PA)- intercalated montmorillonite (PA-MT) adsorbs less water than either K+- or NH+ 4-intercalated montmorillonite (K-MT, NH4-MT). The surface energy of MT was analysed using the van Oss- Chaudhury-Good (VCG) approach based on thewater, benzene and heptane adsorption results. The surface energy between PA-MTand water was less than that of NH4-MT and K-MT. Compared with K-MT and NH4-MT, the surface energy of the Lewis acid portion of PA-MT underwent a more significant decrease, suggesting that the hydration of unexchanged Na+ did not make a discernible contribution. The experimental water-adsorption data were fitted using Langmuir, Brunauer-Emmett-Teller (BET), and Freundlich adsorption models. The Langmuir adsorption models can be used to fit the data for water adsorption on PA-MTacross the entire p/p 0 range. After plotting the experimental data in the linear format of the Freundlichmodel, only one linear region for PA-MTwas observed, indicating a singlewater-adsorption mechanism for PA-MT. When compared with PA in the absence of clay, DRIFT spectroscopy showed that the NH2 bending mode for PA-MT shifted from 1571 cm–1 to 1619.7 cm–1. This suggested an increase in hydrogen bonding (H bonding) between the ammonium group and the interlayer water. Across the entire p/p 0 range, water is suggested to have adsorbed onto PA-MT through H-bonding interactions between the ammonium group and the interlayer water.

Keywords

montmorillonite hydrationsurface-energy analysiswater-adsorption mechanismpolyamine intercalation

Information

Type
Research Article
Information
Clay Minerals , Volume 50 , Issue 4 , September 2015 , pp. 537 - 548
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

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References

Blachier, C., Michot, L., Bihannic, I., Barres, O., Jacquet, A. & Mosquet, M. (2009) Adsorption of polyamine on clay minerals. Journal of Colloid and Interface Science, 336, 599–606.Google Scholar
Brunauer, S., Emmett, P.H. & Teller, E. (1938) Adsorption of gases in multimolecular layers. Journal of the American Chemical Society, 60, 309–319.Google Scholar
Bruton, J.R. & Mclaurine, H.C. (1993) Modified poly-amino acid hydration suppressant proves successful in controlling reactive shales. SPE Paper 26327, Annual Technical Conference and Exhibition of the Society of Petroleum Engineers, Texas, October.Google Scholar
Caenn, R. & Chillingar, G.V. (1996) Drilling fluids: state of the art. Journal of Petroleum Science and Engineering, 14, 221–230.CrossRefGoogle Scholar
Cases, J.M., Bébrend, I., Besson, G., Francois, M., Uriot, J.P., Thomas, F. & Poirier, J.E. (1992) Mechanism of adsorption and desorption of water vapor by homo-ionic montmorillonite. 1. The sodium-exchanged form. Langmuir, 8, 2730–2739.CrossRefGoogle Scholar
Cui, Y.N. & van Jeroen, S.D. (2010) Adsorption of polyetheramines on montmorillonite at High pH. Langmuir, 26, 17210–17217.Google Scholar
Dada, A.O., Olalekan, A.P., Olatunya, A.M. & Dada, O. (2012) Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms studies of equilibrium sorp-tion of Zn 2+ onto phosphoric acid modified rice husk. Journal of Applied Chemistry, 3, 38–45.Google Scholar
Farihahusnah, H., Mohamed, K.A. & Wan M.A.W.D. (2011) Textural characteristics, surface chemistry and activation of bleaching earth: a review. Chemical Engineering Journal, 170, 90–106.Google Scholar
Greenwell, H.C., Harvey, M.J., Boulet, P., Bowden, A.A., Coveney, P.V. & Whiting, A. (2005) Interlayer structure and bonding in nonswelling primary amine interca¬lated clays. Macromolecules, 38, 6189–6200.Google Scholar
Gutjahr, M., Pöppl, A., Böhlmann, W & Böttcher, R. (2001) Electron pair acceptor properties of alkali cations in zeolite, Y. an electron spin resonance study of adsorbed di-tert-butyl nitroxide. Colloids and Surfaces A. Physicochemical and Engineering Aspects, 189, 93–101.Google Scholar
Hatch, C.D., Wiese, J.S., Crane, C.C., Harris, K.J., Kloss, H. G. & Baltrusaitis I (2012) Water adsorption on clay minerals as a function of relative humidity: application of BET and Freundlich adsorption models. Langmuir, 28, 1790–1803.Google Scholar
Jorgensen, T.C (2002) Removal of ammonia from waste-water by ion exchange in the presence of organic compounds.PhD research dissertation, Department of Chemical & Process Engineering, Canterbury University, New Zealand.Google Scholar
Klein, A.L., Aldea, C., Bruton, J.R. & Dobbs, W.R. (2005) Field verification: invert-mud performance from water-based mud in Gulf of Mexico Shelf. SPEPaper 84314, SPE Annual Technical Conference and Exhibition, October, Denver.Google Scholar
Kwok, D.Y & Neumann, A.W. (2000) Contact angle measurements and interpretation: wetting behavior and solid surface tensions for poly(alkylmethacrylate) polymers. Journal of Adhesion Science and Technology, 14, 719–743.Google Scholar
Li, C.S., Xu, F.L., Liu, Q.H. & Xu C.Y (2007) Study on influencing factors of swelling properties of bentonite. Conservation and Utilization of Mineral Resources, 1, 23–25.Google Scholar
Mao, H.J., Guo, Y.T., Wang, G.J. & Yang, C.H. (2010) Evaluation of impact of clay mineral fabrics on hydration process. Rock and Soil Mechanics, 31, 2722–2728.Google Scholar
Médout-Marére, V., Belarbi, H., Thomas, P., Morato, F., Giuntini, J.C. & Douillard, J.M. (1998a) Thermodynamic analysis of the immersion of swelling clay. Journal of Colloid and Interface Science, 202, 139–148.Google Scholar
Médout-Marére, V., Malandrini, H., Zoungrana, T., Douillard, J.M. & Partyka, S. (1998b) Thermodynamic investigation of surface of minerals. Journal of Petroleum Science and Engineering, 20, 223–231.Google Scholar
Morton, E.K., Bomar, B.B., Schiller, M.W., Gallet, J.D., Azar, S.J., Otto, M.J., HansenN.A., Dye, W.M., Shoults, L. & Daugereau, K. (2005) Selection and evaluation criteria for high-performance drilling fluids. SPE Paper 96342, SPE Annual Technical Conference and Exhibition, October, Texas.Google Scholar
Özer, A., Özer, D. & Özer, A. (2004) The adsorption of copper (II) ions on to dehydrated wheat bran (DWB): determination of the equilibrium and thermodynamic parameters. Process Biochemistry, 39, 2183—2191.CrossRefGoogle Scholar
Patel, A.D., Stamatakis, E. & Davis, E. (2001) Shale hydration inhibition agent and method of use. US Patent 6247543. Google Scholar
Patel, A., Stamatakis, S., Young, S. & Friedheim, J. (2007) Advances in inhibitive water-based drilling fluids -can they replace oil-based muds? SPE Paper 106476, SPE International Symposium on Oilfield Chemistry, 28 February—2 March, Texas.Google Scholar
Pironon, J., Pelletier, M., Donato, P.D. & Mosser-Ruck, R. (2003) Characterization of smectite and illite by, F.I. spectroscopy of interlayer NH+4 cations. Clay Minerals, 38,201–211.Google Scholar
Qu, Y.Z., Lai, X.Q., Zou, L.F. & Su, Y.N. (2009) Polyoxyalkyleneamine as shale inhibitor in water-based drilling fluids. Applied Clay Science, 44, 265–268.Google Scholar
Rojas, J.C., Clark, D.E., Greene, B. & Zhang, J. (2006) Optimized salinity delivers improved drilling per-formance. AADE 2006 Fluids Conference. Google Scholar
Rosa, R.S., Rosa, A., Farias, S.B., Garcia, M.H. & Coelho, A. D.S. (2005) A new inhibitive water-based fluid: a completely cationic system. SPE Paper 94523, SPE Latin American and Caribbean Petroleum Engineering Conference, 20–23.June, Rio de Janeiro, Brazil.Google Scholar
Salles, F., Bildstein, O., Douillard, J.M., Jullien, M. & Van Damme, H. (2007) Determination of the driving force for the hydration of the swelling clays from compu¬tation of the hydration energy of the interlayer cations and the clay layer. Journal of Physical Chemistry, 111, 13170–13176.Google Scholar
Shang, S.B., Horne, R.N. & Ramey, H.J. (1995) Water vapor adsorption on geothermal reservoir rocks. Geothermics, 24, 523—540.Google Scholar
Souza, C.E.C.D., Lima, A.S. & Nascimento R.S.V (2010) Hydrophobically modified poly(ethylene glycol) as reactive clays inhibitor additive in water-based dril¬ling, fluids. Journal of Applied Polymer Science, 117, 857–864.Google Scholar
Steiger, R.P. & Leung, P.K. (1992) Quantitative determin¬ation of the mechanical properties of shales. SPE Paper 18024, SPE Drilling Engineering, 7, 181–185.Google Scholar
Van Oss, C.J., Good, R.J. & Chaudhury, M.K. (1988) Additive and nonadditive surface tension components and the interpretation of contact angles. Langmuir, 4, 884–891.Google Scholar
Venkatraman, A., Hesse, M.A., Lake L.W & Johns, R.T. (2014) Analytical solutions for flow in porous media with multicomponent cation exchange reactions. Water Resources Research, 1—17.Google Scholar
Wang, L., Liu, S.Y., Wang, T. & Sun, D.J. (2011) Effect of poly(oxypropylene) diamine adsorption on hydration and dispersion of montmorillonite particles in aqueous solution. Colloids and Surfaces A, 381, 41–47.Google Scholar
Young, S. & Iskander, G.R. (2006) Drilling performance and environmental compliance — resolution of both with a unique water-based fluid. SPE/IADC Paper 103967, SPE/IADC Indian Drilling Technology Conference and Exhibition, October, Mumbai.Google Scholar
Zhong, H.Y., Qiu, Z.S., Huang, W.A. & Cao, J. (2011) Shale inhibitive properties of polyether diamine in water-based drilling fluid. Journal of Petroleum Science and Engineering, 78, 510–515.Google Scholar