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Synthesis and optical properties of composites based on ternary Zn1–x Cdx S nanoparticles enclosed in a layered octosilicate

Published online by Cambridge University Press:  27 February 2018

Y. Chen ,
Z. Yu ,
G. Yu  and
Y. Yan
Y. Chen*
Affiliation:
College of Chemistry, NanchangUniversity; Jiangxi Provincial Key Laboratory of New Energy Chemistry, Nanchang, 330031 P.R., China
Z. Yu
Affiliation:
College of Chemistry, NanchangUniversity; Jiangxi Provincial Key Laboratory of New Energy Chemistry, Nanchang, 330031 P.R., China
G. Yu
Affiliation:
College of Chemistry, NanchangUniversity; Jiangxi Provincial Key Laboratory of New Energy Chemistry, Nanchang, 330031 P.R., China
Y. Yan
Affiliation:
College of Chemistry, NanchangUniversity; Jiangxi Provincial Key Laboratory of New Energy Chemistry, Nanchang, 330031 P.R., China
*
*E-mail: yfchen@ncu.edu.cn
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Abstract

In order to improve the optical properties and enhance the stability of Zn1–x Cdx S nanoparticles, which are important optoelectrical materials, the ternary Zn1–x CdxS nanoparticles were enclosed in a layered octosilicate by a three-step process, namely (i) protonation of Naoctosilicate, (ii) ion-exchange in order to introduce Zn and Cd ions into the interlayer space, and (iii) addition of S2– to form Zn1–x Cdx S particles in the interlayer space of the octosilicate. The basal spacing (~10 Å) of the final ZnCdS-Oct-n (n = 1, 2, 3, 4) composites noticeably increased in comparison with that of the precursor H-Oct (7.5 Å). This may be attributed to the incorporation of larger size Zn1–x Cdx S particles into the interlayer space of H-Oct. The UV-visible spectra of the composites suggested that the transmission band-edges gradually shifted to low energy with increasing molar ratio of Cd/Zn. Moreover, the transmission band-edges of the composites are between those of layered Octosilicate, ZnS, and CdS. TEM observation confirmed that the size of Zn1–x Cdx S nanoparticles enclosed in the layered silicate was about ~3–5 nm.

Keywords

Zn1–x CdxSNa-octosilicatesoptical propertiescomposites

Information

Type
Research Article
Information
Clay Minerals , Volume 49 , Issue 5 , December 2014 , pp. 703 - 716
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2014

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