Hostname: page-component-6bb9c88b65-k72x6 Total loading time: 0 Render date: 2025-07-23T17:30:05.541Z Has data issue: false hasContentIssue false

Sintering behaviour of Tunisian clay–degreaser mixtures: valorizing Weslatiya clay with chamotte as a quartz sand substitute

Published online by Cambridge University Press:  14 July 2025

Mohamed Krichen
Affiliation:
University of Sfax, IPEIS, Sfax, Tunisia Faculty of Sciences, University of Gafsa, LAM3E, Gafsa, Tunisia
Hatem Ksibi*
Affiliation:
University of Sfax, IPEIS, Sfax, Tunisia Faculty of Sciences, University of Gafsa, LAM3E, Gafsa, Tunisia
*
Corresponding author: Hatem Ksibi; Email: hatem.ksibi@ipeis.usf.tn

Abstract

A clay from Weslatiya that is widely used in Tunisian ceramic production has abundant reserves but generates significant waste, posing environmental concerns if not handled appropriately. This study explores the valorization of this local clay by incorporating ceramic waste (chamotte) and quartz sand to produce eco-friendly materials, in line with sustainability and circular economy principles. X-ray diffraction and scanning electron microscopy analyses reveal that incorporating chamotte at levels exceeding 15% by weight improves the material’s properties. The Young’s modulus of the composite increases to 80 GPa, more than 2.5 times that of the basic clay. Chamotte can replace up to 30% of quartz sand without significantly affecting densification or porosity while preserving structural integrity. This approach offers flexibility in terms of material composition, enhancing performance and promoting sustainability by reusing waste materials for high-performance ceramics in industrial applications.

Information

Type
Article
Copyright
© The Author(s), 2025. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland.

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

Footnotes

Associate Editor: Asuman Turkmenoglu

References

Abid, S., Bouaziz, M. & Ksibi, H. (2009) Cracking cone fracture after cold compaction of argillaceous particles. Bulletin of Materials Science, 32, 607610.Google Scholar
Alonso-Santurde, R., Coz, A., Viguri, J. & Andrés, A. (2011) Recycling of foundry by-products in the ceramic industry: green and core sand in clay bricks. Construction and Building Materials, 27, 97106.Google Scholar
Baccari, N., Boussema, M.R., Lamachère, J. & Nasri, S. (2007) Efficiency of contour benches, filling-in and silting-up of a hillside reservoir in a semi-arid climate in Tunisia. Comptes Rendus Géoscience, 340, 3848.Google Scholar
Bennour, A., Mahmoudi, S., Srasra, E., Boussen, S. & Htira, N. (2015) Composition, firing behavior and ceramic properties of the Sejnène clays (northwest Tunisia). Applied Clay Science, 115, 3038.Google Scholar
Chen, L., Chen, X., Yang, X., Bi, P., Ding, X., Huang, X. & Wang, H. (2020) Effect of calcium carbonate on the mechanical properties and microstructure of red clay. Advances in Materials Science and Engineering, 2020, 5298186.Google Scholar
Davidge, R.W. (1974) Effects of microstructure on the mechanical properties of ceramics. Pp. 447468 in: Fracture Mechanics of Ceramics (R.C. Bradt, D.P.H. Hasselman & Lange, F.F., editors). Springer, Boston, MA, USA.Google Scholar
Djangang, C., Elimbi, A., Melo, U., Lecomte, G., Nkoumbou, C., Soro, J. et al. (2007) Sintering of clay–chamotte ceramic composites for refractory bricks. Ceramics International, 34, 12071213.Google Scholar
Hajjaji, W., Moussi, B., Hachani, M., Medhioub, M., Lopez-Galindo, A., Rocha, F. et al. (2010) The potential use of Tithonian–Barremian detrital deposits from central Tunisia as raw materials for ceramic tiles and pigments. Applied Clay Science, 48, 552560.Google Scholar
Húlan, T., Štubňa, I., Ondruška, J., Csáki, Š., Lukáč, F., Mánik, M. et al. (2020) Young’s modulus of different illitic clays during heating and cooling stage of firing. Materials, 13, 4968.Google Scholar
Húlan, T., Štubňa, I., Kaljuvee, T. & Knapek, M. (2021) Young’s modulus of illitic clay in the temperature region of quartz transition. Journal of Thermal Analysis and Calorimetry, 147, 77017707.Google Scholar
Hyeon-Myeong, H., Park, Y., Kim, H., Ko, J. & Lee, H. (2020) Effect of milling ball size on the densification and optical properties of transparent Y2O3 ceramics. Ceramics International, 47, 46814687.Google Scholar
Krichen, M., Baklouti, S., Bonnet, J.P. & Bouaziz, J. (2008) Mineralogy and firing behavior of a clay raw material from Weslatiya (Tunisia). Silicates Industriels, 73, 185190.Google Scholar
López-Perales, J., Sánchez-Rodríguez, R., Suárez-Suárez, D. & Rodríguez, E.A. (2023) Fired electrical porcelain scrap (chamotte waste) recycling and reuse as an alternative raw material for sustainable porcelain stoneware production. Journal of Cleaner Production, 434, 140385.Google Scholar
Lorente-Ayza, M., Orts, M., Pérez-Herranz, V. & Mestre, S. (2015) Role of starch characteristics in the properties of low-cost ceramic membranes. Journal of the European Ceramic Society, 35, 23332341.Google Scholar
Luz, A., Huger, M. & Pandolfelli, V. (2011) Hot elastic modulus of Al2O3–SiC–SiO2–C castables. Ceramics International, 37, 23352345.Google Scholar
Maalla, I., Boussen, S., Fagel, N. & Gaied, M.E. (2021) Incorporation of siliceous sand and lignite tailings from Miocene deposits (Zeramdine, eastern Tunisia) in clay bricks and ceramic tiles: technological feasibility. Arabian Journal of Geosciences, 14, 282.Google Scholar
Mahmoudi, S., Bennour, A., Meguebli, A., Srasra, E. & Zargouni, F. (2016) Characterization and traditional ceramic application of clays from the Douiret region in south Tunisia. Applied Clay Science, 127–128, 7887.Google Scholar
Martín-Márquez, J., Rincón, J.M. & Romero, M. (2010). Effect of microstructure on mechanical properties of porcelain stoneware. Journal of the European Ceramic Society, 30, 30633069.Google Scholar
Medeiros, V.S.C., Pedroti, L.G., Mendes, B.C., Pitanga, H.N. & Da Silva, T.O. (2019) Study of mixtures using simplex design for the addition of chamotte in clay bricks. International Journal of Applied Ceramic Technology, 16, 23492361.Google Scholar
Mymrin, V., Alekseev, K., Catai, R.E., Nagalli, A., Aibuldinov, Y.K., Bekturganov, N.S. et al. (2015) Red ceramics from composites of hazardous sludge with foundry sand, glass waste, and acid-neutralization salts. Journal of Environmental Chemical Engineering, 4, 753761.Google Scholar
Nigay, P., Cutard, T. & Nzihou, A. (2016) The impact of heat treatment on the microstructure of a clay ceramic and its thermal and mechanical properties. Ceramics International, 43, 17471754.Google Scholar
Romero, M. & Pérez, J.M. (2015) Relation between the microstructure and technological properties of porcelain stoneware. A review. Materiales de Construcción, 65, e065.Google Scholar
Salah, I.B., Jemai, M.B.M., Sdiri, A., Slim, N.S. & Boughdiri, M. (2016) Technological characterization and industrial application of Tunisian clays from Makthar area (central Tunisia) in the ceramic industry. Open Journal of Geology, 6, 626639.Google Scholar
Sasmita, F., Wibisono, G., Judawisastra, H. & Priambodo, T.A. (2018) Determination of elastic modulus of ceramics using ultrasonic testing. AIP Conference Proceedings, 1945, 020017.Google Scholar
Štubňa, I., Húlan, T., Kaljuvee, T. & Vozár, L. (2017) Investigation of dynamic mechanical properties of Estonian clay Arumetsa during firing. Applied Clay Science, 153, 2328.Google Scholar
Teng, F., Ou, C. & Hsieh, P. (2013) Measurements and numerical simulations of inherent stiffness anisotropy in soft Taipei clay. Journal of Geotechnical and Geoenvironmental Engineering, 140, 237250.Google Scholar
Worasith, N. & Goodman, B.A. (2023) Clay mineral products for improving environmental quality. Applied Clay Science, 242, 106980.Google Scholar
Zanelli, C., Conte, S., Molinari, C., Soldati, R. & Dondi, M. (2020) Waste recycling in ceramic tiles: a technological outlook. Resources Conservation and Recycling, 168, 105289.Google Scholar
Zawrah, M., Gado, R., Feltin, N., Ducourtieux, S. & Devoille, L. (2016) Recycling and utilization assessment of waste fired clay bricks (grog) with granulated blast-furnace slag for geopolymer production. Process Safety and Environmental Protection, 103, 237251.Google Scholar
Zouaoui, H. & Bouaziz, J. (2017) Performance enhancement of the ceramic products by adding sand, chamotte, and waste brick to a porous clay from Bir Mcherga (Tunisia). Applied Clay Science, 143, 430436.Google Scholar
Zouaoui, H., Lecomte-Nana, G.L., Krichen, M. and Bouaziz, J. (2016) Structure, microstructure, and mechanical features of ceramic products of clay and non-plastic clay mixtures from Tunisia. Applied Clay Science, 135, 112118.Google Scholar