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Crystal Chemistry of Stable and Metastable (Rapidly Quenched) B-Metal Alloy Phases

Published online by Cambridge University Press:  06 March 2019

Bill C. Giessen
Bill C. Giessen*
Affiliation:
Massachusetts Institute of Technology, Cambridge, Massachusetts
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Abstract

The crystal structures of elements and alloy phases in the B-metal region (B2(Zn) to B5(As) groups) have been classified into phase fields determined by their position in the periodic table. The limited number of equilibrium phases with element-like, disordered crystal structures and of extended terminal solid solutions has been more than doubled by the addition of metastable phases produced by ultra-rapid quenching from the melt (splat cooling). Strong structural correlations exist. Some high pressure phases have been included; in some cases, a qualitative discussion from the viewpoint of pseudopotential theory is given.

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Type
Research Article
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Advances in X-Ray Analysis , Volume 12: Seventeenth Annual Conference on Applications of X-ray Analysis, August 21-23, 1968 , 1968 , pp. 23 - 49
Copyright
Copyright © International Centre for Diffraction Data 1968

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