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2 - Thermodynamics with and without Irreversibility

from Part I - Local Systems

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Cristian López
Affiliation:
Université de Lausanne, Switzerland
Olimpia Lombardi
Affiliation:
Universidad de Buenos Aires, Argentina
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Summary

Working inside the control-theoretic framework for understanding thermodynamics, I develop a systematic way to characterize thermodynamic theories via their compatibility with various notions of coarse-graining, which can be thought of as parametrizing an agent’s degree of control of a system’s degrees of freedom, and explore the features of those theories. Phenomenological thermodynamics is reconstructed via the ‘equilibration’ coarse-graining where a system is coarse-grained to a canonical distribution; finer-grained forms of thermodynamics differ from phenomenological thermodynamics only in that some states of a system possess a free energy that can be extracted by reversibly transforming the system (as close as possible) to a canonical distribution. Exceeding the limits of phenomenological thermodynamics thus requires both finer-grained control of a system and finer-grained information about its state. I consider the status of the second law in this framework, and distinguish two versions: the principle that entropy does not decrease, and the Kelvin/Clausius statements about the impossibility of transforming heat to work, or moving heat from a cold body to a hotter body, in a cyclic process. The former should be understood as relative to a coarse-graining, and can be violated given finer control than that coarse-graining permits; the latter is absolute and binds any thermodynamic theory compatible with the laws of physics, even the entirely reversible limit where no coarse-graining is appealed to at all. I illustrate these points via a discussion of Maxwell’s demon.

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The Arrow of Time
From Local Systems to the Whole Universe
, pp. 12 - 55
Publisher: Cambridge University Press
Print publication year: 2025

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