A collision-radiation model of the solid sample cesium sputter ion source led to the rediscovery of anion production by ion-pair production. The model revealed physical processes that may produce high current outputs from such sources and suggested new ways of obtaining high outputs at lower heat and conductive stress to the source. Primary among these solutions is the electron excitation of primary Cs0 recycled from the sample to provide states that efficiently create chosen anions. Here we look at how the processes might apply to gas-fed ion sources.

The dissociation constant for chlorsulfuron {2-chloro-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] carbonyl] benzenesulfonamide} in aqueous solution measured by spectrophotometric titration is 3.58 ± 0.05. Chlorsulfuron was more strongly adsorbed on IRA-400-Cl strong anion exchange resin than on IR-4B-OH weak anion exchange resin or Al2O3 anionotropic adsorbent. Hydrogen bonding was probably responsible for the adsorption observed on IR-120-Na(H) cation exchange resin. No chlorsulfuron was adsorbed on Al2O3 cationotropic absorbent, technical montmorillonite, illite, or kaolinite. Adsorption did occur on organic matter derived from a histosol. Chlorsulfuron was strongly adsorbed on activated charcoal but had little affinity for α-cellulose. Adsorption onto hydrophobic polymeric XAD-2 adsorbent at pH 5.2 was not significant for chlorsulfuron concentrations below 30 μM. No significant adsorption occurred on a variety of mineral soils low in organic matter. Adsorption on a Sharpsburg silty clay loam was inversely related to solution pH. Hydrogen bonding and charge transfer bonds were postulated as the major mechanisms responsible for chlorsulfuron adsorption in soil.

A diode-pumped alkali laser (DPAL) provides the significant promise for high-powered performances. In this paper, a mathematical model is introduced for examination of the kinetic processes of a diode-pumped cesium vapor hollow-core photonic-crystal fiber (HC-PCF) laser, in which the cesium vapor is filled in the center hole of a photonic-bandgap fiber instead of a glass cell. The influence of deleterious processes including energy pooling, photo-ionization, and Penning ionization on the physical features of a fiber DPAL is studied in this report. It has been theoretically demonstrated that the deleterious processes cannot be ignored in a high-powered fiber-DPAL system.

Observation of 80 µA/mm2 C– current from a 0.5-mm-diameter sample compared to 20 µA/mm2 from a 1-mm-diameter sample contradicts the long-held surface ionization hypothesis of cesium sputter ion source operation. Resonant ionization occurs in neutral Cs plasma above a sample in a sputtered pit or well. A collision-radiation model of that plasma followed electronic excitation and radiation relaxation up to the Cs(7d) state. The Cs(5d) metastable state dominates plasma in a 1-mm-diameter well, but high electron densities in narrow wells drive a majority to Cs(7d) and higher. Competitive ionization by Al2 dimers from the sample holder reduces Cs(7s,p) states resonant in ionization energy with C–. Al anions from states above Cs(7p) in narrow wells also diminish radiation cascades to the Cs(7s,p), reducing C–. We tested sample wells of non-ionizing Zn to maintain high ionization efficiency for small samples in narrow wells.

In this paper, a heuristic algorithm based on particle-in-cell (PIC) simulation is introduced to investigate the harmonic generation during the ionization and formation of plasma by a non-relativistic laser field when it propagates through hydrogen atoms. The harmonic generation is considered for the radiative recombination of an ionized electron with its nearest ion. The ionization algorithm is improved by considering the Stark effect and nonzero velocity for ionized electrons. Energy conservation is evaluated during the recombination process. In our code, for the first time, Maxwell's equations are integrated for harmonic fields in a separate mesh using the artificial recombination current as a source term. The simulation results are then used to illustrate the intensity spectrum of generated fields. It is shown that the initial momentum of ionized electrons affects the harmonic spectrum because the energy of radiated photons varies with the electron energy.

In this paper, we study the phenomena of thermo-chemical imbalance in a reactive mono-dimensional flow composed of a mixture of (79% nitrogen N2 and 21% oxygen O2). We are interested in modeling the physicochemical process that may be encountered in hypersonic flows, as vibrational excitation, dissociation and ionization, also the formation of chemical species to higher temperatures behind a detached strong shock. We put a special emphasis on vibrational relaxation model of CVD coupling. At these high temperatures, collisions electrons-atoms become very effective, taking in account the radiation that requires knowledge and modeling of all physicochemical processes (collisional and radiative). The mathematical model of flows at the atmospheric reentry is governed by Euler stationary equations coupled with the chemical kinetics and the radiative transfer equations. Our computational code is based on the finite differences method that used to discretize and resolve the obtained numerical model, where an appropriate mesh is selected in the relaxation zone in order to determine the flow parameters at each grid position

High-energy radiation and particles profoundly affect circumstellar disk gas and solids. We discuss stellar high-energy sources and summarize their effects on circumstellar disks.

This paper addresses the effect of target plasma electrons on the charge state of energetic ions, penetrating a target composed of bound as well as plasma electrons. Dynamic screening of the projectile Coulomb potential by the plasma electrons brings about a depression in the ionization energy of the ionic projectiles, as has been verified experimentally. This in turn makes the ionization cross-sections larger, while making the recombination cross-section smaller, thereby causing an increase in the ion charge state compared to the case of a gas target. The effect of the plasma environment, where the valence electrons are treated as plasma, is illustrated here for a 2 MeV carbon beam penetrating amorphous carbon targets of varying densities.

A scheme is proposed for the acceleration of electrons generated during the ionization of a gas by two laser pulses. The electrons created from the ionization of neutral atoms near the rising edge of the pulse do not gain sufficient energy. If a prepulse is used before the main pulse then the prepulse removes electrons from the outer shells, and the main laser pulse interacts with the electrons in the inner shells of high atomic number gases, such as krypton and argon. The electrons are generated close to the peak of the main laser pulse and gain energy in GeV with a small spread in the energy and low emittance angle.

The charge on plasma ions may fluctuate due to random ionization and recombination processes. The resulting motion has a time dependent Hamiltonian and in simple cases, the ions steadily gain energy. Quantitative rates are estimated for some cases involving high Z plasmas.

Three dimensional Particle-in-Cell (3D-PIC) simulations of electron acceleration in vacuum with radially polarized ultra-intense laser beams have been performed. It is shown that single-cycle laser pulses efficiently accelerate a single attosecond electron bunch to GeV energies. When multi-cycle laser pulses are used, one has to employ ionization of high-Z materials to inject electrons in the accelerating phase at the laser pulse maximum. In this case, a train of highly collimated attosecond electron bunches with a quasi-monoenergetic spectra is produced. A comparison with electron acceleration by Gaussian laser pulses has been done. It is shown that the radially polarized laser pulses are superior both in the maximum energy gain and in the quality of the produced electron beams.

In heavy ion fusion, the compression of the DT pellet requires high intensity beams of ions in the gigaelectron volt energy range. Charge-changing collisions due to intrabeam scattering can have a high impact on the design of adequate accelerator and storage rings. Not only do intensity losses have to be taken into account, but also the deposition of energy on the beam lines after bending magnets, for example, may be nonnegligible. The center-of-mass energy for these intrabeam collisions is typically in the kiloelectron volt range for beam energies in the order of several gigaelectron volts. In this article, we present experimental cross sections for charge transfer and ionization in homonuclear collisions of Ar4+, Kr4+, and Xe4+, and for charge transfer only in homonuclear collisions of Pb4+ and Bi4+. Using a hypothetical 100-Tm synchrotron as an example, expected particle losses are calculated based on the experimental data. The results are compared with expectations for singly charged Bi+ ions, which are usually considered for heavy ion fusion.