The unitary Cayley graph of a ring
$R$ , denoted
$\Gamma \left( R \right)$ , is the simple graph defined on all elements of
$R$ , and where two vertices
$x$ and
$y$ are adjacent if and only if
$x\,-\,y$ is a unit in
$R$ . The largest distance between all pairs of vertices of a graph
$G$ is called the diameter of
$G$ and is denoted by
$\text{diam}\left( G \right)$ . It is proved that for each integer
$n\,\ge \,1$ , there exists a ring
$R$ such that
$\text{diam}\left( \Gamma \left( R \right) \right)=n$ . We also show that
$\text{diam}\left( \Gamma \left( R \right) \right)\in \left\{ 1,2,3,\infty\right\}$ for a ring
$R$ with
${R}/{J\left( R \right)}\;$ self-injective and classify all those rings with
$\text{diam}\left( \Gamma \left( R \right) \right)\,=\,1,\,2,\,3$ , and
$\infty$ , respectively.