Hostname: page-component-7dd5485656-hw7sx Total loading time: 0 Render date: 2025-10-31T17:10:24.879Z Has data issue: false hasContentIssue false
  • English
  • Français

New minerals with a modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part I. Nabimusaite, KCa12(SiO4)4(SO4)2O2F, from larnite rocks of Jabel Harmun, Palestinian Autonomy, Israel

Published online by Cambridge University Press:  02 January 2018

E. V. Galuskin ,
F. Gfeller ,
T. Armbruster ,
I. O. Galuskina ,
Y. Vapnik ,
M. Murashko ,
R. Włodyka  and
P. Dzierżanowski
E. V. Galuskin*
Affiliation:
Department of Geochemistry, Mineralogy and Petrography, Faculty of Earth Sciences, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
F. Gfeller
Affiliation:
Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland
T. Armbruster
Affiliation:
Mineralogical Crystallography, Institute of Geological Sciences, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland
I. O. Galuskina
Affiliation:
Department of Geochemistry, Mineralogy and Petrography, Faculty of Earth Sciences, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
Y. Vapnik
Affiliation:
Department of Geological and Environmental Sciences, Ben-Gurion University of the Negev, POB 653, Beer-Sheva 84105, Israel
M. Murashko
Affiliation:
Saint Petersburg State University, Faculty of Geology, 7-9 Universitetskaya nab., St Petersburg, 199034, Russia
R. Włodyka
Affiliation:
Department of Geochemistry, Mineralogy and Petrography, Faculty of Earth Sciences, University of Silesia, Będzińska 60, 41-200 Sosnowiec, Poland
P. Dzierżanowski
Affiliation:
Institute of Geochemistry, Mineralogy and Petrology, Warsaw University, al. Żwirki i Wigury 93, 02-089 Warsaw, Poland
*
*E-mail: evgeny.galuskin@us.edu.pl
Get access Rights & Permissions [Opens in a new window]

Abstract

The new mineral nabimusaite, KCa12(SiO4)4(SO4)2O2F (R3m, a = 7.1905(4), c = 41.251(3) Å, V = 1847.1(2) Å3, Z = 3), has been discovered in larnite-ye' elimitenodules of pyrometamorphic rocks of the Hatrurim Complex. Nabimusaite is colourless, transparent with a white streak, has a vitreous lustre and does not show luminescence. It is brittle, but shows pronounced parting and imperfect cleavage along (001). Nabimusaite is uniaxial (–), ω= 1.644(2), ε = 1.640(2) (589 nm), nonpleochroic, Mohs' hardness is ∼5 and the calculated density is 3.119 g cm–3. The crystal structure has been solved and refined to R1 = 0.0416. Its artificial analogue is known. The nabimusaite structure may be derived fromthat of hatrurite, also known as the clinker phase 'alite' (C3S = Ca3SiO5), and is built up by an intercalation of three positively charged hatrurite-like modules of composition [Ca12(SiO4)4O2F]3+ withinserted modules of [K(SO4)2]3–. The hatrurite-like modules in nabimusaite are characterized by octahedrally coordinated anion sites and tetrahedrally coordinated cation sites. The structure is representative of the intercalated antiperovskite type. Incontrast to its synthetic analogue, nabimusaite is P-bearing. The shortened bond T–O lengths for one tetrahedral site indicates P preference at the Si2 site, located at the border of the hatrurite-like modules. Significant variations of isomorphous substitutions in nabimusaitesuggest the possibility of other isostructural minerals occurring in Nature. It also seems likely that nabimusaite could serve as a prototype for new advanced synthetic materials, given the discovery of two other new minerals in the Hatrurim Complex with related modular structures, placedin the nabimusaite group. These are zadovite and aradite, as described in a companion paper (Galuskin et al., 2015a).

The mineral assemblage and paragenesis of nabimusaite suggests that nabimusaite formed as a result of the reaction of potassium-enriched, sulfate-bearingmelt with larnite and ellestadite. This contradicts the isochemical model that pyrometamorphic rocks of the Hatrurim Complex formed relatively fast in a practically dry system.

Keywords

nabimusaiteKCa12(SiO4)4(SO4)2O2Fantiperovskitenew mineralstructureRaman SpectrumHatrurim ComplexPalestine Autonomy

Information

Type
Research Article
Information
Mineralogical Magazine , Volume 79 , Issue 5 , October 2015 , pp. 1061 - 1072
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2015

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

Bentor, YK. (editor) (1960) Lexique Stratigraphique International, Asie. Volume III, Section 10.2., Israel. Centre National de la Research Scientifique, Paris.Google Scholar
Beretka, J., de Vito, B., Santoro, L., Sherman, N. and Valenti, G.L. (1993) Hydraulic behaviour of calcium sulfoaluminate-based cements derived from industrial process wastes. Cement and Concrete Research, 23, 1205–1214.CrossRefGoogle Scholar
Bruker (1999) SMART and SAINT-Plus. Versions 6.01. Bruker AXS Inc., Madison, Wisconsin, USA.Google Scholar
Burg, A., Kolodny, Y and Lyakhovsky, V (1999) Hatrurim-2000: the “Mottled Zone” revisited, forty years later. Israel Journal of Earth Sciences, 48, 209–223.Google Scholar
De Noirfontaine, M.-N., Courtial, M., Dunstetter, E, Gasecki, G. and Dignes-Frehel, M. (2012) Tricalcium silicate Ca3Si05 superstructure analysis: a route towards the structure of the Ml polymorph. Zeitschrift fur Kristallographie, 227, 102–112.CrossRefGoogle Scholar
Fayos, J., Glasser, F.P., Howie, R.A., Lachowski, E. and Perez-Mendez, M. (1985) Structure of dodecacal-cium potassium fluoride dioxide terasilicate bis (sulphate), KF.2[Ca6(SO4)(SiO4)2O]: a fluorine-containing phase encountered in cement clinker production process. Ada Crystallographica, C41, 814–816.Google Scholar
Galuskin, E., Galuskina, I., Lazic, B. and Vapnik, Y. (2013) Rock-forming P-bearing ternesite from pyrome-tamorphic rocks of the hatrurim formation, Israel. Mineralogia-Special Papers, 41, 40.Google Scholar
Galuskin, E.V, Galuskina, I.O., Kusz, J. Armbruster, T., Marzec, K.M., Dzierzanowski, P. and Murashko, M. (2014) Vapnikite Ca3UO6-a new double-perovskite mineral from pyrometamorphic larnite rocks of the Jabel Harmun, Palestinian Autonomy, Israel. MineralogicalMagazine, 78, 571–581.Google Scholar
Galuskin, E.V, Gfeller, F., Galuskina, I.O., Pakhomova, A., Armbruster, T., Vapnik, Y, Wlodyka, R., Dzierzanowski, P. and Murashko, M. (2015a) New minerals with modular structure derived from hatrurite from the pyrometamorphic Hatrurim Complex. Part II: Zadovite, BaCa6[(SiO4)(PO4)](PO4)2F, and aradite, BaCa6[(SiO4)(VO4)](VO4)2F, from paralavas of the Hatrurim Basin, Negev Desert, Israel. Mineralogical Magazine, 79, 1073–1087.CrossRefGoogle Scholar
Galuskin, E.V, Gfeller, F, Armbruster, T., Galuskina, I. O., Vapnik, Ye., Dulski, M, Murashko, M., Dzierzanowski, P., Sharygin, VV, Krivovichev, S.V and Wirth, R. (20156) Mayenite supergroup, Part III: Fluormayenite, Cal2All4032 [QFJ, and fluorkyuy-genite, Ca12Al14O32[(H2O)4F2], two new minerals of mayenite supergroup from pyrometamorphic rock of Hatrurim Complex. European Journal ofMineralogy, 27, doi: 10.1127/ejm/2015/0027-2420.CrossRefGoogle Scholar
Galuskina, I.O., Vapnik, Ye., Lazic, B., Armbruster, T., Murashko, M. and Galuskin, E.V (2014a) Harmunite CaFe2O4-a new mineral from the Jabel Harmun, West Bank, Palestinian Autonomy, Israel. American Mineralogist, 99, 965–975.CrossRefGoogle Scholar
Galuskina, I.O., Vapnik, Y, Lazic, B., Armbruster, T., Murashko, M. and Galuskin, E.V (20146) Dzierzanowskite, IMA 2014-032. CNMNC Newsletter No. 21, August 2014, page 802. Mineralogical Magazine, 78, 797–804.Google Scholar
Geller, YI., Burg, A., Halicz, L. and Kolodny, Y (2012) System closure during the combustion metamorphic “Mottled Zone” event, Israel. Chemical Geology, 334, 25–36.CrossRefGoogle Scholar
Gross, S. (1977) The mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel Bulletin, 70, 1–80.Google Scholar
Gross, S. (1984) Occurrence of ye'elimite and ellestadite in an unusual cobble from the “pseudo-conglomerate” of the Hatrurim Basin, Israel. Geological Survey of Israel, Current Research, 1983-84, 1–4.Google Scholar
Hentschel, G., Dent Glasser, L.S. and Lee, C.K. (1983) Jasmundite, Ca22(SiO4)8O4S2, a new mineral. Neues Jahrbuch fur Mineralogie, Monatshefte, 337-343.Google Scholar
Irran, E., Tillmanns, E. and Hentschel, G. (1997) Ternesite, Ca5(SiO4)2SO4, a new mineral from the Ettringer Bellerberg/Eifel, Germany. Mineralogy and Petrology, 60, 121–132.CrossRefGoogle Scholar
Jeffery, J.W. (1952) The crystal structure of tricalcium silicate. Ada Crystallographica, 5, 26–35.CrossRefGoogle Scholar
Kolodny, Y and Gross, S. (1974) Thermal metamorphism by combustion of organic matter: isotopic and petrological evidence. Journal Geology, 82, 489–506.CrossRefGoogle Scholar
Krivovichev, S.V (2008) Minerals with antiperovskite structure: a review. Zeitschrifi fur Kristallographie, 223, 109–113.Google Scholar
Kriiger, H. (2010) Ca5 45Li3-[SiO-Oo-Fj 55 and Ca7K [SiO4]3F3: single-crystal synthesis and structures of two trigonal oxyfluorides. Zeitschrifi fur Kristallographie, 225, 418–424.Google Scholar
Navarro, A. J. and Glasser, FP. (1985) Crystal chemistry of calcium silicates: germinate and chromate analogues of KF-2[Ca6(SO4)(SiO4)2O]. Cement and Concrete Research, 15, 1051–1054.CrossRefGoogle Scholar
Novikov, I., Vapnik, Y and Safonova, I. (2013) Mud volcano origin of the Mottled Zone, South Levant. Geoscience Frontiers, 4, 597–619.CrossRefGoogle Scholar
Sheldrick, G.M. (1996) SADABS. University of Gottingen, Germany.Google Scholar
Sheldrick, G.M. (2008) A short history of SHELX. Ada Crystallographica, A64, 112—122.Google Scholar
Sokol, E.V, Novikov, I.S., Vapnik, Y and Sharygin, VV (2007) Gas fire from mud volcanoes as a trigger for the appearance of high-temperature pyrometamorphic rocks of the Hatrurim Formation (Dead Sea area). Doklady Earth Sciences, 413A, 474–80.CrossRefGoogle Scholar
Sokol, E.V, Novikov, I.S., Zateeva, S.N., Sharygin, VV and Vapnik, Y (2008) Pyrometamorphic rocks of the spurrite-merwinite facies as indicators of hydrocarbon discharge zones (the Hatrurim Formation, Israel). Doklady Earth Sciences, 420, 608–614.CrossRefGoogle Scholar
Sokol, E.V, Kokh, S.N., Vapnik, Y, Thiery, V and Korzhova, S.A. (2014) Natural analogs of belite sulfoaluminate cement clinkers from Negev Desert, Israel. American Mineralogist, 99, 1471–1487.CrossRefGoogle Scholar
Sokolova, E.V, Yamnova, N.A., Egorov-Tismenko, YK. and Khomyakov, A.P. (1984) The crystal structure of a new sodium-calcium-barium phosphate of Na, Ca and Ba (Na5Ca)Ca6Ba(PO4)6F3 . Doklady Akademii Nauk SSSR, 274, 78–83.Google Scholar
Vapnik, Y, Sharygin, VV, Sokol, E.V. and Shagam, R. (2007) Paralavas in a combustion metamorphic complex: Hatrurim Basin, Israel. Reviews in Engineering Geology, 18, 1–21.Google Scholar
Supplementary material: File

Galuskin et al. supplementary material

Table S1

Download Galuskin et al. supplementary material(File)
File 75.3 KB