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Hydrothermal synthesis of gold nanoplates and their structure-dependent LSPR properties

Published online by Cambridge University Press:  13 August 2018

Yanting Liu Open the ORCID record for Yanting Liu [Opens in a new window] ,
Lijun Yang  and
Yajing Shen
Yanting Liu
Affiliation:
Department of Mechanical and Biomedical Engineering, City University of Hong Kong, Hong Kong SAR 999077, China
Lijun Yang
Affiliation:
Key Laboratory of Micro-Systems and Micro-Structures Manufacturing of Ministry of Education, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Yajing Shen*
Affiliation:
Department of Mechanical and Biomedical Engineering, City University of Hong Kong, Hong Kong SAR 999077, China; City University of Hong Kong Shenzhen Research Institute, Shen Zhen 518057, People’s Republic of China; and Key Laboratory of Micro-Systems and Micro-Structures Manufacturing of Ministry of Education, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: yajishen@cityu.edu
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Abstract

We developed a facile hydrothermal method to synthesize gold nanoplates with the assistance of surfactant cetyltrimethylammonium chloride (CTAC). Gold nanostructure shapes from triangular, truncated triangular to hexagonal morphology with different sizes can be obtained by accommodating the molar ratios of the surfactant to the gold precursor ([CTAC]/[HAuCl4]). The edge width of gold nanoplates could also be adjusted from tens to hundreds of nanometers, and even several microns. The growth mechanism analysis reveals that the surfactant CTAC directs and promotes the growth of the tabular {111} facets to form nanoplate structures with the size and shape variations. The structure-dependent localized surface plasmon resonance of different gold nanoplates was theoretically and experimentally explained by finite element method simulation and surface-enhanced Raman scattering (SERS) enhancement, respectively. Based on the Raman spectrum analysis of the marker molecule 4-mercaptobenzoic acid (4-MBA) labeled with different gold nanoplates, it demonstrates that the enhanced SERS performance relies on the different plasmonic properties of the gold nanoplates. Therefore, the gold nanoplates may have potential applications in SERS-based sensing and imaging field.

Keywords

gold nanoplates·triangular structure·localized surface plasmon resonance·surface-enhanced Raman scattering

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Type
Article
Information
Journal of Materials Research , Volume 33 , Issue 18 , 28 September 2018 , pp. 2671 - 2679
Copyright
Copyright © Materials Research Society 2018 

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References

REFERENCES

Murphy, C.J., Sau, T.K., Gole, A.M., Orendorff, C.J., Gao, J., Gou, L., Hunyadi, S.E., and Li, T.: Anisotropic metal nanoparticles: synthesis, assembly, and optical applications. J. Phys. Chem. B 109, 13857 (2005).CrossRefGoogle ScholarPubMed
Kretschmer, F., Mühlig, S., Hoeppener, S., Winter, A., Hager, M.D., Rockstuhl, C., Pertsch, T., and Schubert, U.S.: Survey of plasmonic nanoparticles: From synthesis to application. Part. Part. Syst. Charact. 31, 721 (2014).CrossRefGoogle Scholar
Ruditskiy, A. and Xia, Y.: The science and art of carving metal nanocrystals. ACS Nano 11, 23 (2017).CrossRefGoogle ScholarPubMed
Zhao, P., Li, N., and Astruc, D.: State of the art in gold nanoparticle synthesis. Coord. Chem. Rev. 257, 638 (2013).CrossRefGoogle Scholar
Liu, S. and Tang, Z.: Nanoparticle assemblies for biological and chemical sensing. Coord. Chem. Rev. 257, 638 (2013).Google Scholar
Pérez-Juste, J., Pastoriza-Santos, I., Liz-Marzán, L.M., and Mulvaney, P.: Gold nanorods: Synthesis, characterization and applications. Coord. Chem. Rev. 249, 1870 (2005).CrossRefGoogle Scholar
Dreaden, E.C., Alkilany, A.M., Huang, X., Murphy, C.J., and El-Sayed, M.A.: The golden age: Gold nanoparticles for biomedicine. Chem. Soc. Rev. 41, 2740 (2012).CrossRefGoogle ScholarPubMed
Cui, J., Yang, L., Wang, Y., Mei, X., Wang, W., and Hou, C.: Nanospot soldering polystyrene nanoparticles with an optical fiber probe laser irradiating a metallic AFM probe based on the near-field enhancement effect. ACS Appl. Mater. Interfaces 7, 2294 (2015).CrossRefGoogle ScholarPubMed
Vigderman, L., Khanal, B.P., and Zubarev, E.R.: Functional gold nanorods: Synthesis, self-assembly, and sensing applications. Adv. Mater. 24, 4811 (2012).CrossRefGoogle ScholarPubMed
Skrabalak, S.E., Au, L., Li, X., and Xia, Y.: Facile synthesis of Ag nanocubes and Au nanocages. Nat. Protoc. 2, 2182 (2007).CrossRefGoogle ScholarPubMed
Loo, C., Hirsch, L., Lee, M-H., Chang, E., West, J., Halas, N., and Drezek, R.: Gold nanoshell bioconjugates for molecular imaging in living cells. Opt. Lett. 30, 1012 (2005).CrossRefGoogle ScholarPubMed
Shankar, S.S., Rai, A., Ankamwar, B., Singh, A., Ahmad, A., and Sastry, M.: Biological synthesis of triangular gold nanoprisms. Nat. Mater. 3, 482 (2004).CrossRefGoogle ScholarPubMed
Huang, Y., Ferhan, A.R., Gao, Y., Dandapat, A., and Kim, D-H.: High-yield synthesis of triangular gold nanoplates with improved shape uniformity, tunable edge length and thickness. Nanoscale 6, 6496 (2014).CrossRefGoogle ScholarPubMed
Ah, C.S., Yun, Y.J., Park, H.J., Kim, W-J., Ha, D.H., and Yun, W.S.: Size-controlled synthesis of machinable single crystalline gold nanoplates. Chem. Mater. 17, 5558 (2005).CrossRefGoogle Scholar
Li, C.C., Cai, W.P., Cao, B.Q., Sun, F.Q., Li, Y., Kan, C.X., and Zhang, L.D.: Mass synthesis of large, single-crystal Au nanosheets based on a polyol process. Adv. Funct. Mater. 16, 83 (2006).CrossRefGoogle Scholar
Chen, C-C., Hsu, C-H., and Kuo, P-L.: Effects of alkylated polyethylenimines on the formation of gold nanoplates. Langmuir 23, 6801 (2007).CrossRefGoogle ScholarPubMed
Liu, X., Wu, N., Wunsch, B.H., Barsotti, R.J., and Stellacci, F.: Shape-controlled growth of micrometer-sized gold crystals by a slow reduction method. Small 2, 1046 (2006).CrossRefGoogle ScholarPubMed
Huang, W-L., Chen, C-H., and Huang, M.H.: Investigation of the growth process of gold nanoplates formed by thermal aqueous solution approach and the synthesis of ultra-small gold nanoplates. J. Phys. Chem. C 111, 2533 (2007).CrossRefGoogle Scholar
Chu, H-C., Kuo, C-H., and Huang, M.H.: Thermal aqueous solution approach for the synthesis of triangular and hexagonal gold nanoplates with three different size ranges. Inorg. Chem. 45, 808 (2006).CrossRefGoogle ScholarPubMed
Grzelczak, M., Perez-Juste, J., Mulvaney, P., and Liz-Marzan, L.M.: Shape control in gold nanoparticle synthesis. Chem. Soc. Rev. 37, 1783 (2008).CrossRefGoogle ScholarPubMed
Sau, T.K. and Rogach, A.L.: Nonspherical noble metal nanoparticles: Colloid-chemical synthesis and morphology control. Adv. Mater. 22, 1781 (2010).CrossRefGoogle ScholarPubMed
Yang, Z., Li, Z., Lu, X., He, F., Zhu, X., Ma, Y., He, R., Gao, F., Ni, W., and Yi, Y.: Controllable biosynthesis and properties of gold nanoplates using yeast extract. Nano-Micro Lett. 9, 5 (2016).CrossRefGoogle Scholar
Cui, J., Zhang, J., Wang, X., Barayavuga, T., He, X., Mei, X., Wang, W., Jiang, G., and Wang, K.: Near-field optical characteristics of Ag nanoparticle within the near-field scope of a metallic AFM tip irradiated by SNOM laser. Integr. Ferroelectr. 178, 117 (2017).CrossRefGoogle Scholar
Chen, S., Xu, P., Li, Y., Xue, J., Han, S., Ou, W., Li, L., and Ni, W.: Rapid seedless synthesis of gold nanoplates with microscaled edge length in a high yield and their application in SERS. Nano-Micro Lett. 8, 328 (2016).CrossRefGoogle Scholar
Liu, Y., Zhou, J., Yuan, X., Jiang, T., Petti, L., Zhou, L., and Mormile, P.: Hydrothermal synthesis of gold polyhedral nanocrystals by varying surfactant concentration and their LSPR and SERS properties. RSC Adv. 5, 68668 (2015).CrossRefGoogle Scholar
Ha, T.H., Kim, Y.J., and Park, S.H.: Complete separation of triangular gold nanoplates through selective precipitation under CTAB micelles in aqueous solution. Chem. Commun. 46, 3164 (2010).CrossRefGoogle ScholarPubMed
James, K., O’Toole, M., Patel, D., Zhang, G., Gobin, A., and Keynton, R.: A high yield, controllable process for producing tunable near infrared-absorbing gold nanoplates. RSC Adv. 5, 12498 (2015).CrossRefGoogle Scholar
Personick, M.L. and Mirkin, C.A.: Making sense of the mayhem behind shape control in the synthesis of gold nanoparticles. J. Am. Chem. Soc. 135, 18238 (2013).CrossRefGoogle ScholarPubMed
Rai, A., Singh, A., Ahmad, A., and Sastry, M.: Role of halide ions and temperature on the morphology of biologically synthesized gold nanotriangles. Langmuir 22, 736 (2006).CrossRefGoogle ScholarPubMed
Wuithschick, M., Birnbaum, A., Witte, S., Sztucki, M., Vainio, U., Pinna, N., Rademann, K., Emmerling, F., Kraehnert, R., and Polte, J.: Turkevich in new robes: Key questions answered for the most common gold nanoparticle synthesis. ACS Nano 9, 7052 (2015).CrossRefGoogle ScholarPubMed
Liu, H. and Yang, Q.: A two-step temperature-raising process to gold nanoplates with optical and surface enhanced Raman spectrum properties. CrystEngComm 13, 2281 (2011).CrossRefGoogle Scholar
Liu, Y. and Shen, Y.: Hydrothermal synthesis of gold nanoplates with different size ranges. In Nanotechnology (IEEE-NANO), 2017 IEEE 17th International Conference on IEEE, Vol. 816, Li, G., ed. (IEEE, USA, 2017); pp. 816–817.CrossRefGoogle Scholar
Ji, X., Song, X., Li, J., Bai, Y., Yang, W., and Peng, X.: Size control of gold nanocrystals in citrate reduction: The third role of citrate. J. Am. Chem. Soc. 129, 13939 (2007).CrossRefGoogle ScholarPubMed
Kaur, P. and Chudasama, B.: Single step synthesis of pluronic stabilized IR responsive gold nanoplates. RSC Adv. 4, 36006 (2014).CrossRefGoogle Scholar
Michota, A. and Bukowska, J.: Surface-enhanced Raman scattering (SERS) of 4-mercaptobenzoic acid on silver and gold substrates. J. Raman Spectrosc. 34, 21 (2003).CrossRefGoogle Scholar
Ho, C-H. and Lee, S.: SERS and DFT investigation of the adsorption behavior of 4-mercaptobenzoic acid on silver colloids. Colloids Surf., A 474, 29 (2015).CrossRefGoogle Scholar
Ding, S-Y., Yi, J., Li, J-F., Ren, B., Wu, D-Y., Panneerselvam, R., and Tian, Z-Q.: Nanostructure-based plasmon-enhanced Raman spectroscopy for surface analysis of materials. Nat. Rev. Mater. 1, 16021 (2016).CrossRefGoogle Scholar
Cui, J., Yang, L., and Wang, Y.: Simulation study of near-field enhancement on a laser-irradiated AFM metal probe. Laser Phys. 23, 076003 (2013).CrossRefGoogle Scholar
Johnson, P., Johnson, P.B., and Christy, R.W.: Optical constants of the noble metals. Phys. Rev. B 6, 4370 (1972).CrossRefGoogle Scholar
Álvarez-Puebla, R.A.: Effects of the excitation wavelength on the SERS spectrum. J. Phys. Chem. Lett. 3, 857 (2012).CrossRefGoogle ScholarPubMed
Zhang, Q., Large, N., and Wang, H.: Gold nanoparticles with tipped surface structures as substrates for single-particle surface-enhanced Raman spectroscopy: Concave nanocubes, nanotrisoctahedra, and nanostars. ACS Appl. Mater. Interfaces 6, 17255 (2014).CrossRefGoogle ScholarPubMed